High frequency dielectric study on the hydrogen bonding interaction on 1,5-pentanediol+1,4-dioxane binary mixtures

被引：2
|
作者：
Garad, Nitin P. [1 ]
Saknure, Shankar H. [1 ]
Dongre, Daiwashala G. [1 ]
Kumbharkhane, Ashok C. [1 ]
机构：
[1] Swami Ramanand Teerth Marathwada Univ, Sch Phys Sci, Nanded 431606, Maharashtra, India
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2024年 / 102卷 / 06期
关键词：
dielectric constant; TDR; relaxation time; thermodynamic parameters; Kirkwood correlation factor; RELAXATION;
D O I：
10.1139/cjc-2023-0190
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex dielectric permittivity spectra (CPS) of a binary mixture of 1,5-pentanediol (1,5-PD) with 1,4-dioxane (1,4-DX) were determined using time-domain reflectometry in the frequency range of 10 MHz to 30 GHz. The experimental CPS data were fitted to the Cole-Davidson equation using a nonlinear least squares fit method to determine the dielectric relaxation parameters. The intermolecular interactions in the binary liquids were studied through the Kirkwood correlation factor, excess parameters, thermodynamic parameters, and Bruggeman's factor.
引用
收藏
页码：391 / 396
页数：6
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