High frequency dielectric study on the hydrogen bonding interaction on 1,5-pentanediol+1,4-dioxane binary mixtures

被引：2
|
作者：
Garad, Nitin P. [1 ]
Saknure, Shankar H. [1 ]
Dongre, Daiwashala G. [1 ]
Kumbharkhane, Ashok C. [1 ]
机构：
[1] Swami Ramanand Teerth Marathwada Univ, Sch Phys Sci, Nanded 431606, Maharashtra, India
来源：
CANADIAN JOURNAL OF CHEMISTRY | 2024年 / 102卷 / 06期
关键词：
dielectric constant; TDR; relaxation time; thermodynamic parameters; Kirkwood correlation factor; RELAXATION;
D O I：
10.1139/cjc-2023-0190
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The complex dielectric permittivity spectra (CPS) of a binary mixture of 1,5-pentanediol (1,5-PD) with 1,4-dioxane (1,4-DX) were determined using time-domain reflectometry in the frequency range of 10 MHz to 30 GHz. The experimental CPS data were fitted to the Cole-Davidson equation using a nonlinear least squares fit method to determine the dielectric relaxation parameters. The intermolecular interactions in the binary liquids were studied through the Kirkwood correlation factor, excess parameters, thermodynamic parameters, and Bruggeman's factor.
引用
收藏
页码：391 / 396
页数：6
相关论文
共 19 条
  • [1] Dielectric characterization and molecular interaction behaviour in binary mixtures of amides with dimethylsulphoxide and 1,4-dioxane
    Sengwa, R. J.
    Sankhla, Sonu
    Khatri, Vinita
    JOURNAL OF MOLECULAR LIQUIDS, 2010, 151 (01) : 17 - 22
  • [2] Study of Dielectric Relaxation and Hydrogen Bonding Interaction of 1, 4-Butanediol-1, 4-Dioxane Mixture using TDR Technique
    Garad, Nitin P.
    Saknure, Shankar H.
    Gubre, Ashwini G.
    Kumbharkhane, Ashok C.
    INDIAN JOURNAL OF PURE & APPLIED PHYSICS, 2023, 61 (03) : 158 - 164
  • [3] Dielectric study of acrylonitrile-1,4-dioxane mixtures using a Time Domain Reflectometry
    Dongre, D. G.
    Gubre, A. G.
    Garad, N. P.
    Saknure, S. H.
    Kumbharkhane, A. C.
    PHYSICS AND CHEMISTRY OF LIQUIDS, 2025, 63 (01) : 13 - 21
  • [4] Dielectric and hydrogen bonding studies of butyronitrile with 1,4-dioxane using a time-domain reflectometry
    Dongre, D. G.
    Deshmukh, A. R.
    Garad, N. P.
    Gubre, A. G.
    Saknure, S. H.
    Kumbharkhane, A. C.
    CANADIAN JOURNAL OF PHYSICS, 2024, 102 (06) : 352 - 357
  • [5] Static dielectric constants of the binary mixtures of N-methylformamide with water, ethyl alcohol, ethylene glycol, dimethylsulphoxide, acetone and 1,4-dioxane
    Sengwa, R. J.
    Sankhla, Sonu
    Khatri, Vinita
    PHILOSOPHICAL MAGAZINE LETTERS, 2010, 90 (07) : 463 - 470
  • [6] Exploring dielectric relaxation in 1,2-propanediol and 1,4-dioxane binary mixtures: time-domain reflectometry analysis
    Garad, Nitin P.
    Kumbharkhane, Neha A.
    Kumbharkhane, Ashok C.
    CANADIAN JOURNAL OF CHEMISTRY, 2025, 103 (01) : 19 - 26
  • [7] Dielectric properties of binary mixtures of three butanediols with 1,4-dioxane and 2-ethyl-1-hexanol at T=298.2 K
    Gilani, A. Ghanadzadeh
    Ghanadzadeh, H.
    Bahrpaima, Kh.
    Ranjkesh, A.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (08) : 967 - 972
  • [8] High-frequency dielectric study on the hydrogen bonding interaction on aqueous Cyanoacetamide
    Mallick, S.
    Malathi, M.
    Kumbharkhane, A. C.
    JOURNAL OF MOLECULAR LIQUIDS, 2018, 272 : 264 - 270
  • [9] Dielectric data of binary mixtures of 1,2-butanediol with 2-ethyl-1-hexanol and 1,4-dioxane at T = (298.2, 308.2, and 318.2) K
    Gilani, A. Ghanadzadeh
    Gilani, H. Ghanadzadeh
    Ansari, M.
    Ojani, N.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2012, 44 (01) : 44 - 50
  • [10] Dielectric analysis of binary systems of primary diols with 1-hexanol and 1,4-dioxane at various temperatures
    Gilani, A. Ghanadzadeh
    Gilani, H. Ghanadzadeh
    Ansari, M.
    JOURNAL OF MOLECULAR LIQUIDS, 2014, 196 : 270 - 279
12