Effects of Carbon Nanotubes on Formation of Disinfection By-Products during Chlorination of Natural Organic Matters

被引：0
|
作者：
Li H. [1 ]
Chen X. [2 ]
You M. [1 ]
Sun W. [1 ]
机构：
[1] College of Environmental Sciences and Engineering, Peking University, The Key Laboratory of Water and Sediment Sciences, Ministry of Education, Beijing
[2] Shenzhen Key Laboratory for Heavy Metal Pollution Control and Reutilization, School of Environment and Energy, Peking University Shenzhen Graduate School, Shenzhen
来源：
Beijing Daxue Xuebao (Ziran Kexue Ban)/Acta Scientiarum Naturalium Universitatis Pekinensis | 2021年 / 57卷 / 02期
关键词：
Carbon nanomaterials; Chlorination; Disinfect by-products; Natural organic matters;
D O I：
10.13209/j.0479-8023.2020.115
中图分类号：
学科分类号：
摘要：
Multi-wall carbon nanotubes (CNTs) and natural organic matters (NOMs) were chosen as target pollutants in this study. The effects of CNTs on the formation of disinfection by-products during chlorination of different types of NOMs (Suwannee river standard humic acid (HASR) and Suwannee river standard fulvic acid (FASR)) were investigated. Compared with the single system of CNTs or NOMs, the presence of CNTs increased the yields and initial formation rates of trihalomethanes (THMs) and halogenated acetic acids (HAAs) in the binary systems. Both CNTs and NOMs could serve as precursors of disinfection by-products, leading to more active sites for chlorination in NOMs-CNTs system. Therefore, the yields and initial formation rates of binary systems increased. Moreover, the initial formation rate of THMs and HAAs formed by HASR were higher than those formed by FASR in the absence and presence of CNTs. This was due to the higher aromaticity of HASR than FASR, which favored the attack of hypochlorous acid. In addition, the adsorption amount of HASR to CNTs was greater than FASR, which resulted in its stronger effects on the formation of disinfection by-products than FASR. © 2021 Peking University.
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页码：299 / 310
页数：11
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共 46 条
  • [21] Vikesland P J, Fiss E M, Wigginton K R, Et al., Halogenation of bisphenol-A, triclosan, and phenols in chlorinated waters containing iodide, Environmen-tal Science & Technology, 47, 13, pp. 6764-6772, (2013)
  • [22] Lane R F, Adams C D, Randtke S J, Et al., Chlorina-tion and chloramination of bisphenol A, bisphenol F, and bisphenol A diglycidyl ether in drinking water, Water Research, 79, pp. 68-78, (2015)
  • [23] Hyung H, Kim J H., Natural organic matter (NOM) adsorption to multi-walled carbon nanotubes: effect of NOM characteristics and water quality parameters, Environmental Science & Technology, 42, 12, pp. 4416-4421, (2008)
  • [24] Zhang S, Shao T, Karanfil T., The effects of dissolved natural organic matter on the adsorption of synthetic organic chemicals by activated carbons and carbon nanotubes, Water Research, 45, 3, pp. 1378-1386, (2011)
  • [25] Yang Kun, Xing Baoshan, Adsorption of fulvic acid by carbon nanotubes from water, Environmental Pollution, 157, 4, pp. 1095-1100, (2009)
  • [26] Zhang H C, Huang C H., Oxidative transformation of triclosan and chlorophene by manganese oxides, Environmental Science & Technology, 37, 11, pp. 2421-2430, (2003)
  • [27] Kang S H, Xing B S., Humic acid fractionation upon sequential adsorption onto goethite, Langmuir, 24, 6, pp. 2525-2531, (2008)
  • [28] 2
  • [29] Hur J, Lee B M, Shin H S., Microbial degradation of dissolved organic matter (DOM) and its influence on phenanthrene-DOM interactions, Chemosphere, 85, 8, pp. 1360-1367, (2011)
  • [30] Weiling Sun, Jing Xia, Si Li, Et al., Effect of natural organic matter (NOM) on Cu(II) adsorption by multi-walled carbon nanotubes: relationship with NOM properties, Chemical Engineering Journal, 200-202, pp. 627-636, (2012)
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