Microstructures and properties of Cu/Fe/Kovar composites prepared with cu-coated Kovar alloy powders

被引:8
作者
Lu, Jinxia [1 ]
Gan, Xueping [1 ]
Liu, Chaoqiang [1 ]
机构
[1] Cent South Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
基金
中国国家自然科学基金;
关键词
Kovar alloys; Electroless plating; Thermal properties; Coefficient of thermal expansion; Microstructure;
D O I
10.1016/j.matlet.2024.136218
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To improve the thermal conductivities of Kovar alloys (4J50), Fe and Cu coatings were prepared on surfaces of one of Kovar alloys (4J50) powders by electroless plating and Cu/Fe/Kovar composites were hot-pressing sintered. The Fe interlayer is prepared to decrease the mutual diffusion between the Cu coating and the Kovar alloy matrix. Since the existence of Cu network in the composites, the composites present a better thermal conductivity than Kovar alloys. The Cu/Fe/Kovar composites containing 10 wt% and 20 wt% Cu have a thermal conductivity of 24.7 W/(m.K) and 25.8 W/(m.K), respectively, which is 48 % and 54 % higher than that of the Kovar alloy (16.7 W/(m.K)). Due to the presence of Cu network, the coefficients of thermal expansion of the composites is slightly higher than that of the Kovar alloy. The method reported in this study can be also applied to improve the thermal conductively of other Kovar alloys.
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页数:4
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共 11 条
[1]   Bonding strength of Invar/Cu clad strips fabricated by twin-roll casting process [J].
Chen, Peng ;
Huang, Hua-gui ;
Ji, Ce ;
Zhang, Xu ;
Sun, Zhong-hua .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2018, 28 (12) :2460-2469
[2]   Microstructure and mechanical properties of the vacuum diffusion bonding joints of 4J29 kovar alloy and 316L stainless steel using pure cobalt interlayer [J].
Fang, Y. J. ;
Jiang, X. S. ;
Mo, D. F. ;
Song, T. F. ;
Luo, Z. P. .
VACUUM, 2019, 168
[3]   Numerical and Experimental Research on Fluid Flow, Solidification, and Bonding Strength During the Twin-Roll Casting of Cu/Invar/Cu Clad Strips [J].
Ji, Ce ;
Huang, Huagui ;
Zhang, Xu ;
Zhao, Ridong .
METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2020, 51 (04) :1617-1631
[4]   Cu-Containing Fe-Ni Corrosion-Resistant Alloys Designed by a Cluster-Based Stable Solid Solution Model [J].
Li, Baozeng ;
Wang, Qing ;
Wang, Yingmin ;
Li, Chunyan ;
Qiang, Jianbing ;
Ji, Chunjun ;
Dong, Chuang .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2012, 43A (02) :544-554
[5]   Atomic mobilities, zero-flux planes and flux reversals in fcc Cu-Fe-Ni alloys [J].
Liu, Yajun ;
Zhang, Lijun ;
Du, Yong ;
Sheng, Guang ;
Wang, Jiang ;
Liang, Dong .
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2011, 35 (03) :376-383
[6]   Synthesis and thermal expansion of ZrO2/ZrW2O8 composites [J].
Lommens, P ;
De Meyer, C ;
Bruneel, E ;
De Buysser, K ;
Van Driessche, I ;
Hoste, S .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2005, 25 (16) :3605-3610
[7]   Effect of Invar particle size on microstructures and properties of the Cu/Invar bi-metal matrix composites fabricated by SPS [J].
Nie, Qiangqiang ;
Chen, Guohong ;
Wang, Bing ;
Yang, Lei ;
Zhang, Jianhua ;
Tang, Wenming .
JOURNAL OF ALLOYS AND COMPOUNDS, 2022, 891
[8]   Effects of rolling and annealing on microstructures and properties of Cu/Invar electronic packaging composites prepared by powder metallurgy [J].
Wu, Dan ;
Yang, Lei ;
Shi, Chang-dong ;
Wu, Yu-cheng ;
Tang, Wen-ming .
TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2015, 25 (06) :1995-2002
[9]   Microstructure and mechanical properties of single-crystal diamond/Kovar alloy joints brazed with an AgCuTi metal filler [J].
Wu, Haoyue ;
Li, Xuewen ;
Tu, Bing ;
Zhang, Lin ;
Pan, Pan ;
Li, Yulong .
DIAMOND AND RELATED MATERIALS, 2023, 138
[10]   Metallization of Al2O3 ceramic by magnetron sputtering Ti/Mo bilayer thin films for robust brazing to Kovar alloy [J].
Xin, Chenglai ;
Liu, Wenbo ;
Li, Ning ;
Yan, Jiazhen ;
Shi, Sanqiang .
CERAMICS INTERNATIONAL, 2016, 42 (08) :9599-9604