CsPbBr3 perovskite quantum dots-based Janus membrane with multifunction of luminescence, magnetism and aeolotropic electroconductivity

被引:4
|
作者
Huo, Xintong [1 ]
Xie, Yunrui [2 ,3 ]
Sheng, Yuqi [1 ]
Shao, Hong [3 ]
Hu, Yaolin [1 ]
Yang, Liu [1 ]
Qi, Haina [1 ]
Ma, Qianli [3 ]
Yu, Wensheng [3 ]
Dong, Xiangting [1 ,2 ,3 ]
机构
[1] Changchun Univ Sci & Technol, Coll Mat Sci & Engn, Changchun 130022, Peoples R China
[2] Changchun Univ Sci & Technol, Chongqing Res Inst, Chongqing 401135, Peoples R China
[3] Changchun Univ Sci & Technol, Key Lab Appl Chem & Nanotechnol Univ Jilin Prov, Changchun 130022, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
Electrospinning; Perovskite quantum dots; Multifunctional properties; Janus microfiber; Janus membrane; Partition;
D O I
10.1016/j.jcis.2024.04.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Lead halide perovskite quantum dots (QDs) are promising semiconductors for next -generation photoelectric devices. However, the development of perovskite QDs-based multifunctional materials still needs to be addressed in order to further advance the application of perovskite QDs. Herein, a successful synthesis of Janus microfibers array Janus membrane (JMAJM) with up -down structure and multifunction of luminescence, magnetism and electroconductivity is firstly achieved based on CsPbBr 3 QDs through a parallel electrospinning. JMAJM comprises up -down two layers tightly bonded together. The up -layer of JMAJM is luminescence/magnetism Janus microfibers array (L/M-JMAJM) constructed by [CsPbBr 3 /polymethyl methacrylate (PMMA)]//[CoFe 2 O 4 / PMMA] Janus microfibers as building elements. The down -layer of JMAJM is luminescence/electroconductivity Janus microfibers array (L/E-JMAJM) fabricated by [CsPbBr 3 /PMMA]//[polyaniline (PANI)/PMMA] Janus microfibers as building elements. Two independent microcosmic regions are designed and realized in a Janus microfiber, confining luminescence with magnetic or conductive substances into their respective regions, thus minimizing adverse effects of other dark -colored functional substances on the fluorescence of CsPbBr 3 QDs. This peculiar Janus microfiber enables the effective separation and high integration of CsPbBr 3 QDs with other functional substances. The up -down structure of JMAJM ensures a high integration of luminescence, magnetism and conductivity. Meanwhile, JMAJM addresses the environmental instability of CsPbBr 3 QDs while simultaneously endows perovskite QDs-based materials with additional functions to realize multifunction. Under ultraviolet excitation, fluorescence characteristics of the CsPbBr 3 QDs in JMAJM are maintained, exhibiting a vibrant green emission at 517 nm. Meanwhile, JMAJM achieves a maximum saturation magnetization of 20.32 emu & sdot;g - 1 micro -partition with macro -partition in JMAJM receives superior concurrent luminescence -magnetic -conductive multifunction. This work provides a novel idea and strategy for advancing perovskite QDs-based multifunctional materials. , high conductance of 10 -2 S and aeolotropic electroconductivity degree of 10 7 . The combination of micro -partition with macro -partition in JMAJM receives superior concurrent luminescence -magnetic -conductive multifunction. This work provides a novel idea and strategy for advancing perovskite QDs-based multifunctional materials.
引用
收藏
页码:615 / 628
页数:14
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