Study on Performance of Self-supporting Oxygen Evolution Electrocatalyst for Rapid Prepared Stainless Steel Mesh

被引:0
|
作者
Li Y. [1 ]
Xiong T. [1 ]
Wei J. [1 ]
Muhammad-Sadeeq B. [1 ]
机构
[1] College of Materials Science and Engineering, Hunan University, Changsha
基金
中国国家自然科学基金;
关键词
Catalysis; Overpotential; Oxygen Evolution Reaction(OER); Scalable preparation; Self-supporting electrocatalyst; Water splitting;
D O I
10.16339/j.cnki.hdxbzkb.2021.06.007
中图分类号
学科分类号
摘要
The 304 stainless steel mesh was treated in a boiling solution containing 2 mol•L-1 nickel source for 120 s to obtain a self-supporting electrocatalyst(denoted SS/Ni-OH2M-120s) with excellent Oxygen Evolution Reaction(OER) performance. This self-supporting electrocatalyst facilitated industrialization and scale production. The overpotential of SS/Ni-OH2M-120s electrocatalyst obtained at the current density of 10 mA•cm-2 was 214 mV, which was about 127 mV lower than that of the blank 304 stainless steel mesh. After the constant potential polarization for 10 h at a current density of 20 mA•cm-2, the catalytic performance displayed no obvious change, indicating excellent stability. When SS/Ni-OH2M-120s anode was combined with the Pt mesh cathode(Pt-Mesh//SS/Ni-OH2M-120s) to make overall splitting water, a decomposition voltage of 1.61 V at the current density of 10 mA•cm-2 was achieved, which was 0.23 V lower than the commercial Pt-Mesh//IrO2 /SS. © 2021, Editorial Department of Journal of Hunan University. All right reserved.
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页码:45 / 51
页数:6
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共 22 条
  • [1] ZHANG H B, AN P F, ZHOU W, Et al., Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction, Science Advances, 4, 1, (2018)
  • [2] WANG L, ZHOU Q, PU Z H, Et al., Surface reconstruction engineering of cobalt phosphides by Ru inducement to form hollow Ru-RuPx-CoxP pre-electrocatalysts with accelerated oxygen evolution reaction, Nano Energy, 53, pp. 270-276, (2018)
  • [3] SHAN J Q, GUO C X, ZHU Y H, Et al., Charge-redistribution-enhanced nanocrystalline Ru@ IrOx electrocatalysts for oxygen evolution in acidic media, Chem, 5, 2, pp. 445-459, (2019)
  • [4] SUEN N T, HUNG S F, QUAN Q, Et al., Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives, Chemical Society Reviews, 46, 2, pp. 337-365, (2017)
  • [5] JIAO Y, ZHENG Y, JARONIEC M, Et al., Design of electrocatalysts for oxygen and hydrogen-involving energy conversion reactions, Chemical Society Reviews, 44, 8, pp. 2060-2086, (2015)
  • [6] WANG P C, LEI Q, LIU S, Et al., MoS<sub>2</sub>-based electrocatalysts for hydrogen evolution and the prospect of hydrogen energy technology, Chemical Industry and Engineering Progress, 38, 1, pp. 278-290, (2019)
  • [7] PETRIE J R, COOPER V R, FREELAND J W, Et al., Enhanced bifunctional oxygen catalysis in strained LaNiO<sub>3</sub> perovskites, Journal of the American Chemical Society, 138, 8, pp. 2488-2491, (2016)
  • [8] ZHAO D D, ZHANG N, BU L Z, Et al., Recent advances in non-noble metal nanomaterials for oxygen evolution electrocatalysis, Journal of Electrochemistry, 24, 5, pp. 455-465, (2018)
  • [9] TANG D, MABAYOJE O, LAI Y Q, Et al., In situ growth of Fe(Ni)OOH catalyst on stainless steel for water oxidation, Chemistry Select, 2, 7, pp. 2230-2234, (2017)
  • [10] YU F S, LI F, SUN L C., Stainless steel as an efficient electrocatalyst for water oxidation in alkaline solution, International Journal of Hydrogen Energy, 41, 10, pp. 5230-5233, (2016)