Liquid-liquid phase of imidazolium-based ionic liquids in n-butyl acetate plus n-butanol mixtures: Experimental measurements, quality testing, phase stability, thermodynamic modeling

The ester n -butyl acetate is an important chemical compound produced by esterification with n-butanol and used as solvent for pigments, vegetable oils and fats, and in the production of varnishes, coatings, waxes and resins. This work investigated the use of ionic liquids (ILs) as solvents in separation processes involving these substances. The ionic liquid 1-butyl-3-methylimidazolium chloride ([BMIM][Cl]) was synthesized, while 1-ethyl-3methylimidazolium ethyl sulfate ([EMIM][EtSO 4 ]) and 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIM] [BF 4 ]) were purchased. The liquid - liquid equilibrium (LLE) was analyzed based on the experimental measurements (binodal curve, tie -lines), sigma-profiles analysis (COSMOTherm), experimental data quality tests, phase stability and thermodynamic modeling with NRTL for the n -butyl acetate + n-butanol + IL ([BMIM][Cl], [EMIM] [EtSO 4 ], [EMIM][BF 4 ]) systems at 298.15 K and 101.3 kPa. Experimental results indicated that the studied systems had the LLE phase behavior of type I. Experiments and calculations showed that [EMIM][EtSO 4 ] and [BMIM][Cl] had the best capacities to separate the azeotrope n-butanol and n -butyl acetate. All systems showed separation factors values higher than unity. Low deviations, in the compositions of both liquid phases, indicate that the NRTL model was able to analyze the phase stability and model the phase behavior of the n -butyl acetate + n-butanol + IL systems using gamma -gamma approach.