Stimulated X-ray emission spectroscopy

被引：2

作者：

Bergmann, Uwe ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Phys, Madison, WI 53706 USA

来源：

PHOTOSYNTHESIS RESEARCH | 2024年 / 162卷 / 2-3期

关键词：

X-ray spectroscopy; X-ray free-electron laser; Stimulated X-ray emission; Electronic structure; Manganese; X-ray laser; FREE-ELECTRON LASER; PHOTOSYSTEM-II; TRANSITION; DYNAMICS; ATOMS; MOLECULES;

D O I：

10.1007/s11120-024-01080-y

中图分类号：

Q94 [植物学];

学科分类号：

071001 ;

摘要：

We describe an emerging hard X-ray spectroscopy technique, stimulated X-ray emission spectroscopy (S-XES). S-XES has the potential to characterize the electronic structure of 3d transition metal complexes with spectral information currently not reachable and might lead to the development of new ultrafast X-ray sources with properties beyond the state of the art. S-XES has become possible with the emergence of X-ray free-electron lasers ( XFELs) that provide intense femtosecond X-ray pulses that can be employed to generate a population inversion of core-hole excited states resulting in stimulated X-ray emission. We describe the instrumentation, the various types of S-XES, the potential applications, the experimental challenges, and the feasibility of applying S-XES to characterize dilute systems, including the Mn4Ca cluster in the oxygen evolving complex of photosystem II.

引用

页码：371 / 384

页数：14

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