Comparative study of synthesis methods and pH-dependent adsorption of methylene blue dye on UiO-66 and NH2-UiO-66

被引：14
作者：
Daneshgar H. [1 ,2 ]
Sojdeh S. [1 ]
Salehi G. [1 ]
Edrisi M. [2 ]
Bagherzadeh M. [1 ]
Rabiee N. [3 ,4 ]
机构：
[1] Department of Chemistry, Sharif University of Technology, Tehran
[2] Institute of Biochemistry and Biophysics (IBB), University of Tehran, Tehran
[3] Center for Molecular Medicine and Innovative Therapeutics, Murdoch University, Perth, 6150, WA
[4] School of Chemistry, Damghan University, Damghan
来源：
Chemosphere | 2024年 / 353卷
关键词：
Adsorption kinetic; Methylene blue dye; MOFs; NH[!sub]2[!/sub]-UiO-66; UiO-66;
D O I：
10.1016/j.chemosphere.2024.141543
中图分类号：
学科分类号：
摘要：
Metal-organic frameworks (MOFs) are highly promising adsorbents with notable properties such as elevated adsorption capacities and versatile surface design capabilities. This study introduces two distinct synthesis methods, one lasting 1 h and the other 24 h, for UiO-66 and NH2-UiO-66. While both methods yield structures with comparable crystallinity and morphology, the adsorption performance of the cationic methylene blue dye varies at different pH levels. Despite the 24 h synthesis time being optimal for maximum adsorption in both MOFs, the relative difference in NH2-UiO-66 adsorption percentage at different times suggests reduced dependency on synthesis time for this property. Notably, NH2-UiO-66 exhibits consistent and effective performance across three pH levels, warranting further investigation into its adsorption kinetics and isotherm. The achievement of high adsorption efficiency coupled with a significantly reduced synthesis time underscores the importance of developing simplified synthetic methods, essential for enhancing the practical applicability of MOFs in diverse applications. © 2024 The Authors
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共 57 条
[31]  
Mantasha I., Shahid M., Saleh H.A., Qasem K.M., Ahmad M., A novel sustainable metal organic framework as the ultimate aqueous phase sensor for natural hazards: detection of nitrobenzene and F− at the ppb level and rapid and selective adsorption of methylene blue, CrystEngComm, 22, 22, pp. 3891-3909, (2020)
[32]  
Mashentseva A.A., Seitzhapar N., Barsbay M., Aimanova N.A., Alimkhanova A.N., Zheltov D.A., Sadyrbekov D.T., Adsorption isotherms and kinetics for Pb (II) ion removal from aqueous solutions with biogenic metal oxide nanoparticles, RSC advances, 13, 38, pp. 26839-26850, (2023)
[33]  
Mohammadi A.A., Alinejad A., Kamarehie B., Javan S., Ghaderpoury A., Ahmadpour M., Ghaderpoori M., Metal-organic framework Uio-66 for adsorption of methylene blue dye from aqueous solutions, Int. J. Environ. Sci. Technol., 14, 9, pp. 1959-1968, (2017)
[34]  
Mondal S., Purkait M.K., De S., Advances in Dye Removal Technologies, (2018)
[35]  
Morris W., Wang S., Cho D., Auyeung E., Li P., Farha O.K., Mirkin C.A., Role of modulators in controlling the colloidal stability and polydispersity of the UiO-66 metal–organic framework, ACS applied materials & interfaces, 9, 39, pp. 33413-33418, (2017)
[36]  
Naushad M., Alqadami A.A., AlOthman Z.A., Alsohaimi I.H., Algamdi M.S., Aldawsari A.M., Adsorption kinetics, isotherm and reusability studies for the removal of cationic dye from aqueous medium using arginine modified activated carbon, J. Mol. Liq., 293, (2019)
[37]  
Obayomi K.S., Lau S.Y., Zahir A., Meunier L., Zhang J., Dada A.O., Rahman M.M., Removing Methylene Blue from Water: a study of sorption effectiveness onto nanoparticles-doped activated carbon, Chemosphere, 313, (2023)
[38]  
Pirzadeh K., Esfandiari K., Ghoreyshi A.A., Rahimnejad M., CO 2 and N 2 adsorption and separation using aminated UiO-66 and Cu 3 (BTC) 2: a comparative study, Kor. J. Chem. Eng., 37, pp. 513-524, (2020)
[39]  
Purohit H.S., Zhang G.G., Gao Y., Detecting crystallinity in amorphous solid dispersions using dissolution testing: considerations on properties of drug substance, drug product, and selection of dissolution media, J. Pharmaceut. Sci., 112, 1, pp. 290-303, (2023)
[40]  
Qin J., Dou Y., Zhou J., Candelario V.M., Andersen H.R., Helix-Nielsen C., Zhang W., Photocatalytic valorization of plastic waste over zinc oxide encapsulated in a metal–organic framework, Adv. Funct. Mater., (2023)
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