Kinetic analysis and modeling of oxidation reaction in bio-oil

被引：0

作者：

Yu F. ^{[1
,2
]}

Sun J. ^{[1
,2
,3
]}

Yang H. ^{[1
,2
]}

Chen W. ^{[1
,2
]}

机构：

[1] Department of Process Equipment and Control Engineering, Hebei University of Technology, Tianjin

[2] National-Local Joint Engineering Laboratory for Energy Conservation in Chemical Process Integration and Resources Utilization, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin

[3] Department of Mechanics, School of Mechanical Engineering, Tianjin University, Tianjin

来源：

Taiyangneng Xuebao/Acta Energiae Solaris Sinica | 2021年 / 42卷 / 10期

关键词：

Bio-oil; Kinetic analysis; Kinetic model; Kinetic parameter; Oxidation reaction;

D O I：

10.19912/j.0254-0096.tynxb.2019-1414

中图分类号：

学科分类号：

摘要：

Taking the pyrolysis bio-oil solution of cotton stalk as the research object, on the basis of kinetic analysis, the kinetic model of oxidation reaction based on COD is established. The dynamic parameters of oxidation reaction are calculated combined with the experimental data, and the kinetic model curves of oxidation reaction are obtained. The results show that in the oxidation process, the COD of the bio-oil solution decreases exponentially. When the reaction time is 0-60 min range, the bio-oil solution is rapidly oxidized, while the oxidation rate decreases gradually in 60-120 min range. The oxidation process basically is finished at 120 min. The correlation coefficients between the model curves and the experimental values are all above 0.9, indicating that the model can well predict the oxidation reaction results of organic compounds in the solution of biological oil. © 2021, Solar Energy Periodical Office Co., Ltd. All right reserved.

引用

页码：331 / 335

页数：4

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