NEW HETEROLIGAND OCTAHEDRAL CLUSTER COMPLEXES OF MOLYBDENUM AND TUNGSTEN

被引：0

作者：

Pronin, A. S. ^{[1
]}

Sukhikh, T. S. ^{[1
]}

Mironov, Y. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2024年 / 65卷 / 08期

基金：

俄罗斯科学基金会;

关键词：

molybdenum; tungsten; octahedral cluster complexes; crystal structure; X= BR; LUMINESCENCE; CHEMISTRY; HALIDES; OXIDE;

D O I：

10.1134/S0022476624080043

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The (Bu4N)(2)[{Mo6I8}(CN)(5)(OEt)]center dot 2H(2)O and (Bu4N)(2)[{W6I8}(CN)(4)(OEt)(2)]center dot H2O center dot EtOH cluster complexes are prepared by the reaction of (Bu4N)(2)[{M6I8}I-6] (M = Mo, W) with NaCN in ethanol and subsequent recrystallization from an aqueous ethanol solution. The structure of both compounds is determined by XRD. The external ligand environment of the anions contains CN- and OEt- ligands. The behavior of the complexes in an aqueous solution is studied by electron spectroscopy.

引用

页码：1513 / 1520

页数：8

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