Synthesis of 1,8-Naphthalimide Water-Based Fluorescent Polymer and Application in High Yield Pulp

被引：0
作者：
Pei J. [1 ]
Zhang G. [1 ]
Guo M. [1 ]
机构：
[1] Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science and Technology, Xi'an
来源：
Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering | 2019年 / 35卷 / 06期
关键词：
Fluorescent polymer; Naphthalimide; Water-solubility; Yellowing inhibitor;
D O I：
10.16865/j.cnki.1000-7555.2019.0163
中图分类号：
学科分类号：
摘要：
A naphthalimide fluorescent monomer (FBA) was synthesized successively by amidation reaction and substitution reaction using 4-bromo-1,8-naphthalic anhydride as raw material. Subsequently, a naphthalimide fluorescent polymer (PFBA) was obtained through free radical polymerization with FBA, acrylamide (AM) and methacryloyloxyethyl trimethylammonium chloride (DMC). The structure of the product was characterized by FT-IR and 1H-NMR, and its optical properties were analyzed by the ultraviolet spectra and fluorescence spectra. The morphology of the product was analyzed by SEM. The property of yellowing inhibitation on paper was analyzed by UV accelerated aging test. After UV aging for 36 h, the whiteness of paper coated with FBA and PFBA is decreased less than that of the blank paper about 1.19 ISO% and 3.64 ISO%, respectively. The results show that PFBA exhibit a good water solubility and could effectively inhibit yellowing of the paper. © 2019, Editorial Board of Polymer Materials Science & Engineering. All right reserved.
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页码：16 / 22
页数：6
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共 12 条
  • [1] Zhang G.H., Wang P., Xiang R., Et al., Synthesis and application of polymer light stabilizer based on coumarin fluorescent brightener, Polymer Materials Science & Engineering, 30, 3, pp. 25-30, (2014)
  • [2] Hu C., Zhu W., Lin W., Et al., Synthesis and luminescence of novel emitting copolymers, Synth. Metals, 102, pp. 1129-1130, (1999)
  • [3] Sun J.F., Qian Y., Synthesis and fluorescent properties of water-soluble 1, 8-naphthalimide dendron, Chinese Journal of Organic Chemistry, 35, 5, pp. 1104-1111, (2015)
  • [4] Sawa M., Hsu T.L., Itoh T., Et al., Glycoproteomic probes for fluorescent imaging of fucosylated glycans in vivo, Proc. Natl. Acad. Sci. USA, 103, pp. 12371-12376, (2006)
  • [5] Coya C., Blanco R., Juarez R., Et al., Synthesis and tunable emission of novel polyfluorene co-polymers with 1, 8-naphthalimide pendant groups and application in a single layer-single component white emitting device, Eur. Polym. J., 46, pp. 1778-1789, (2010)
  • [6] Georgiev N.I., Dimitrova M.D., Mavrova A.T., Et al., Synthesis, fluorescence-sensing and molecular logic of two water-soluble 1, 8-naphthalimides, . Spectrochim. Acta, A, 183, pp. 7-16, (2017)
  • [7] Georgiev N.I., Sakr A.R., Bojinov V.B., Design and synthesis of a novel PET and ICT based 1, 8-naphthalimide FRET bichromophore as a four-input disabled-enabled-or logic gate, Sens. Actuators, B, 221, pp. 625-634, (2015)
  • [8] Huang H.L., Song J.H., Ge H., Et al., Preparation of 1, 8-naphthalimide derivatives/cellulose composite hydrogels and their fluorescent performance, Plastics Additives, 3, pp. 42-47, (2016)
  • [9] Liu L.J., Zhang G.H., Preparation and properties of polymerizable fluorescent materials, Polymer Materials Science & Engineering, 27, 12, pp. 4-8, (2011)
  • [10] Cao C.B., Yu X.L., Wang Z.F., Et al., Polymeric fluorescent brighteners, Journal of Chemical Industry and Engineering, 56, 3, pp. 375-381, (2005)
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