KI interface modification improves efficiency of perovskite solar cells

被引:0
|
作者
Jiang T. [1 ]
Zhang F. [1 ]
Wang Y. [1 ]
Yang Y. [1 ]
Zhao D. [1 ,2 ]
Wu L. [1 ,2 ]
Wang W. [1 ,2 ]
Zhang J. [1 ,2 ]
Hao X. [1 ,2 ]
机构
[1] Institute of New Energy and Low Carbon Technology, School of Materials Science and Engineering, Sichuan University, Chengdu
[2] Engineering Research Center of Alternative Energy Materials & Devices, Chengdu
关键词
interface modification; KI; perovskite solar cells; SnO[!sub]2[!/sub] electronic transport layer;
D O I
10.11817/j.issn.1672-7207.2022.08.006
中图分类号
学科分类号
摘要
The planar-structured perovskite solar cell was prepared through addition of KI intercalation layer between the SnO2 electron transport layers(ETLs)/perovskite layer prepared at low temperature. The interfacial modification effect of KI intercalation layer for the SnO2 ETLs/perovskite layer, and the influences on the properties of perovskite film and the device performance of perovskite solar cells were investigated. The results show that the addition of KI interlayer facilitates the grain growth of perovskite film and thus improves the interfacial carrier transport efficiency at ETLs/perovskite absorber. Herein, the overall performances, especially the power conversion efficiency, for both rigid and flexible solar cells are significantly optimized after the involvement of KI interlayer, mainly due to the improved open-circuit voltage(Voc) and fill factor(FF), despite the short-circuit current density(Jsc) slightly decreases. The average power conversion efficiencies of rigid devices and flexible ones increase from 17.71% and 14.52 % to 18.46% and 17.46 %, respectively. © 2022 Central South University of Technology. All rights reserved.
引用
收藏
页码:2869 / 2877
页数:8
相关论文
共 27 条
  • [1] ZHOU Zhe, SUN Kaiwen, JIANG Liangxing, Et al., Research progress on recycling technology of end-of-life silicon photovoltaic modules, Journal of Central South University (Science and Technology), 51, 12, pp. 3279-3288, (2020)
  • [2] JIANG Shaojian, WANG Tao, PENG Haoyi, Et al., Thermogravimetric and combustion dynamics of moulding fuel of woodiness and cornstalk, Journal of Central South University(Science and Technology), 44, 10, (2013)
  • [3] YAO Xin, DING Yanli, ZHANG Xiaodan, Et al., A review of the perovskite solar cells, Acta Physica Sinica, 64, 3, (2015)
  • [4] STRANKS S D, EPERON G E, GRANCINI G, Et al., Electron-hole diffusion lengths exceeding 1 micrometer in an organometal trihalide perovskite absorber[J], Science, 342, 6156, (2013)
  • [5] CHAI Lei, ZHONG Min, Recent research progress in perovskite solar cells, Acta Physica Sinica, 65, 23, (2016)
  • [6] FENG Jing, Mechanical properties of hybrid organicinorganic CH<sub>3</sub>NH<sub>3</sub>BX<sub>3</sub>(B=Sn, Pb
  • [7] X=Br, I) perovskites for solar cell absorbers, APL Materials, 2, 8, (2014)
  • [8] KITAZAWA N, WATANABE Y, NAKAMURA Y., Optical properties of CH<sub>3</sub>NH<sub>3</sub>PbX<sub>3</sub> (X = halogen) and their mixed-halide crystals, Journal of Materials Science, 37, pp. 3585-3587, (2002)
  • [9] HUANG Lingyi, LAMBRECHT W R L., Electronic band structure, phonons, and exciton binding energies of halide perovskites CsSnCl<sub>3</sub>, CsSnBr<sub>3</sub>, and CsSnI<sub>3</sub>, Physical Review B, 88, 16, (2013)
  • [10] COLELLA S, MOSCONI E, FEDELI P, Et al., MAPbI<sub>3-x</sub>Cl<sub>x</sub> mixed halide perovskite for hybrid solar cells: the role of chloride as dopant on the transport and structural properties [J], Chemistry of Materials, 25, 22, (2013)