CO2-induced gate-opening structural transition process of a porous coordination polymer revealed by solid-state 13C NMR

被引：1
|
作者：
Kurihara, Takuya [1 ]
Souri, Yue [1 ]
Inukai, Munehiro [2 ]
Mizuno, Motohiro [1 ,3 ,4 ]
机构：
[1] Kanazawa Univ, Grad Sch Nat Sci & Technol, Div Mat Chem, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[2] Tokushima Univ, Grad Sch Technol Ind & Social Sci, 2-1 Minami Josanjima Cho, Tokushima 7708506, Japan
[3] Kanazawa Univ, Nanomat Res Inst, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
[4] Kanazawa Univ, Inst Frontier Sci Initiat, Kakuma Machi, Kanazawa, Ishikawa 9201192, Japan
来源：
CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 38期
关键词：
METAL-ORGANIC FRAMEWORKS; BREATHING TRANSITIONS; ADSORPTION; DYNAMICS; SPECTROSCOPY; MECHANISM; INSIGHTS;
D O I：
10.1039/d4cc01180e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study investigates the gate-opening closed-to-open-pore structural transition of a porous coordination polymer induced by CO2 adsorption. Solid-state( 13)C NMR examination of adsorbed CO2 and framework dynamics reveals the surface adsorption state of the closed structure below the transition pressure and an intermediate structure during the transition process.
引用
收藏
页码：5074 / 5077
页数：4
相关论文
共 49 条
  • [1] Structural Unit of Polymer Crystallization in Dilute Solution As Studied by Solid-State NMR and 13C Isotope Labeling
    Wang, Shijun
    Yuan, Shichen
    Chen, Wei
    Zhou, Yang
    Hong, You-lee
    Miyoshi, Toshikazu
    MACROMOLECULES, 2018, 51 (21) : 8729 - 8737
  • [2] Chemical Reactions and Their Kinetics of atactic-Polyacrylonitrile As Revealed by Solid-State 13C NMR
    Liu, Xiaoran
    Makita, Yuta
    Hong, You-lee
    Nishiyama, Yusuke
    Miyoshi, Toshikazu
    MACROMOLECULES, 2017, 50 (01) : 244 - 253
  • [3] Structural Identification of Polyacrylonitrile during Thermal Treatment by Selective 13C Labeling and Solid-State 13C NMR Spectroscopy
    Wang, Yusong
    Xu, Lianghua
    Wang, Mozhen
    Pang, Wenmin
    Ge, Xuewu
    MACROMOLECULES, 2014, 47 (12) : 3901 - 3908
  • [4] Structural characterization of supramolecular assemblies by 13C spin dilution and 3D solid-state NMR
    Habenstein, Birgit
    Loquet, Antoine
    Giller, Karin
    Becker, Stefan
    Lange, Adam
    JOURNAL OF BIOMOLECULAR NMR, 2013, 55 (01) : 1 - 9
  • [5] Structural investigations of polyurethane and silk-polyurethane composite fiber studied by 13C solid-state NMR spectroscopy
    Asakura, Tetsuo
    Ibe, Yusuke
    Jono, Takaki
    Matsuda, Hironori
    Kuwabara, Nobuo
    Naito, Akira
    JOURNAL OF APPLIED POLYMER SCIENCE, 2021, 138 (40)
  • [6] Structural characterization of 13C-enriched humins and alkali-treated 13C humins by 2D solid-state NMR
    van Zandvoort, Ilona
    Koers, Eline J.
    Weingarth, Markus
    Bruijnincx, Pieter C. A.
    Baldus, Marc
    Weckhuysen, Bert M.
    GREEN CHEMISTRY, 2015, 17 (08) : 4383 - 4392
  • [7] Stoichiometry and Packing Structure of Poly(lactic acid) Stereocomplex as Revealed by Solid-State NMR and 13C Isotope Labeling
    Zhou, Wenxuan
    Wang, Kun
    Wang, Shijun
    Yuan, Shichen
    Chen, Wei
    Konishi, Takashi
    Miyoshi, Toshikazu
    ACS MACRO LETTERS, 2018, 7 (06) : 667 - 671
  • [8] A structural and dynamic study of poly(vinyl alcohol) in the gel state by solid-state 13C NMR and 1H pulse NMR
    Kanekiyo, M
    Kobayashi, M
    Ando, I
    Kurosu, H
    Ishii, T
    Amiya, S
    JOURNAL OF MOLECULAR STRUCTURE, 1998, 447 (1-2) : 49 - 59
  • [9] Chemical reactions in poly(acrylonitrile-co-itaconic acid) during stabilization as revealed by solid-state NMR spectroscopy and 13C isotope labeling
    Ma, Jiayang
    Zheng, Zhaoxi
    Tang, Yijing
    Nagashima, Hiroki
    Miyoshi, Toshikazu
    CARBON, 2023, 215
  • [10] The relation of structural mobility and water sorption of soil organic matter studied by 1H and 13C solid-state NMR
    Jaeger, Alexander
    Bertmer, Marko
    Schaumann, Gabriele E.
    GEODERMA, 2016, 284 : 144 - 151
12345