Effect of Organosilane-Modified Polycarboxylate Superplasticizers on Grain Size of Calcium Silicate Hydrate Seeds

被引：0
|
作者：
Wang X. [1 ]
Qian S. [1 ]
Wang Z. [2 ]
Liu X. [2 ]
Zheng C. [2 ]
机构：
[1] Jiangsu China Railway ARIT New Materials Co., Ltd, Jiangsu Province Engineering Research Center (ARIT) of Concrete Polymer Additives, Nanjing
[2] Faculty of Materials and Manufacturing, Beijing University of Technology, Beijing
来源：
Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society | 2022年 / 50卷 / 11期
关键词：
Calcium silicate hydrate; Early hydration; Polycarboxylate superplasticizers; Portland cement; Seeds;
D O I：
10.14062/j.issn.0454-5648.20220262
中图分类号：
学科分类号：
摘要：
In order to obtain stable and dispersed calcium silicate hydrate (C-S-H) crystal nucleus, improve its crystal nucleus-inducing effect on cement hydration, and realize the efficient utilization of cement clinker. Polycarboxylate superplasticizers (PCE) with different proportions of acrylic acid (AA) and silane group (KH570) were prepared via free radical polymerization to disperse calcium silicate hydrate (C-S-H) seeds. The corresponding C-S-H/PCE seeds were synthesized by a solution precipitation method. The grain size/size distribution, the stability of C-S-H/PCE seeds and the bonding mode of PCE on C-S-H interface were investigated. The results show that the PCE with an appropriate proportion of KH570 can effectively control the grain size of C-S-H/PCE seeds. The adsorption mode of PCE on C-S-H surface changes from Ca2+ complexation to a more stable Si-O-Si chemical bond, and the grain size of C-S-H/PCE seeds firstly decreases and then increases with the increase of KH570 ratio. At a KH570 to AA ratio of 1, the adsorption layer thickness of PCE on the surface of C-S-H is 2.5 nm, the grain size of C-S-H/PCE seeds is 60 nm and the stability is optimum. The PCE undergoes an intramolecular dehydration condensation process under alkaline condition with further increasing the proportion of KH570, forming a reticulated silicone resin structure, which is unfavorable for the regulation of grain size of C-S-H/PCE seeds. © 2022, Editorial Department of Journal of the Chinese Ceramic Society. All right reserved.
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页码：2818 / 2825
页数：7
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共 22 条
  • [11] SCHONLRIN M, PLANK J., A TEM study on the very early crystallization of CSH in thepresence of polycarboxylate superplasticizers: transformation from initial C-S-H globules to nanofoils, Cem Concr Res, 106, 4, pp. 33-39, (2018)
  • [12] PLANK J, SCHONLRIN M, KANCHANASON V., Study on the early crystallization ofcalcium silicate hydrate (C-S-H) in the presence of polycarboxylate superplasticizers, J Organomet Chem, 869, 8, pp. 227-232, (2018)
  • [13] WANG Fang, KONG Xiangming, WANG Dongmin, Et al., The effects of nano-C-S-H with different polymer stabilizers on earlycementhydration, J Am Ceram Soc, 102, 3, pp. 5103-5116, (2019)
  • [14] KANCHANASON V, PLANK J., Role of pH on the structure, composition and morphology of C-S-H-PCE nanocomposites and their effect on early strength development of Portland cement, Cem Concr Res, 102, 12, pp. 90-98, (2017)
  • [15] OROZCO C A, CHUN B W, GENG G., Characterization of the bonds developed between calcium silicate hydrate and polycarboxylate based superplasticizer with silylfunctionalities, Langmuir, 33, 14, pp. 3404-3412, (2017)
  • [16] FAN Wei, STOFFELBACH F, RIEGER J, Et al., A new class of organosilane-modified polycarboxylate superplasticizers with low sulfate sensitivity, Cem Concr Res, 42, 1, pp. 166-172, (2012)
  • [17] HE Yongjia, LV Linnv, SHAN Zhanfei, Et al., J Chin Ceram Soc, 41, 2, pp. 218-223, (2013)
  • [18] KIYOFUMI K, TOYOHARU N, HITOSHI O, Et al., Deteriorated hardened cement paste structure analyzed by XPS and <sup>29</sup>Si NMR techniques, Cem Concr Res, 52, 10, pp. 190-195, (2013)
  • [19] MA Baoguo, PENG Yi, TAN Hongbo, Et al., Effect of hydroxypropyl-methyl cellulose ether on rheology of cement paste plasticized by polycarboxylate superplasticizer, Constr Build Mater, 160, 1, pp. 341-350, (2018)
  • [20] ZHENG Dafeng, QIU Xueqing, LOU Hongming, J Chem Ind Eng, 1, pp. 256-259, (2008)
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