Phase Transitions under the Electric Field in Ternary Ferroelectric Solid Solutions of Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 near the Morphotropic Phase Boundary: Electric Approach

被引：1

作者：

Iwata, Makoto ^{[1
]}

Suzuki, Soma ^{[1
]}

Takikawa, Yoshinori ^{[1
]}

Nakamura, Keiichiro ^{[2
]}

Echizenya, Kazuhiko ^{[2
]}

机构：

[1] Nagoya Inst Technol, Dept Phys Sci & Engn, Nagoya 4668555, Japan

[2] JFE Mineral & Alloy Co Ltd, Chiba 2600826, Japan

来源：

CRYSTALS | 2024年 / 14卷 / 02期

基金：

日本学术振兴会;

关键词：

ferroelectric; relaxor; critical endpoint; electric field; morphotropic phase boundary; SYSTEM SINGLE-CRYSTAL; PIEZOELECTRIC PROPERTIES; ELECTROMECHANICAL RESPONSE; DIELECTRIC BEHAVIOR; TEMPERATURE; TRANSFORMATION; ORDER;

D O I：

10.3390/cryst14020121

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Temperature-field phase diagrams in the [001]c and [011]c directions in the cubic coordinate in 24%Pb(In1/2Nb(1/2))O-3-46%Pb(Mg1/3Nb2/3)O-3-30%PbTiO3 (24PIN-46PMN-30PT) and 31PIN-43PMN-26PT near the morphotropic phase boundary have been clarified by measuring the temperature dependences of permittivity under an electric field. Field-induced intermediate orthorhombic and tetragonal phases have been newly found in 24PIN-46PMN-30PT and 31PIN-43PMN-26PT, respectively. The temperature dependences of the remanent polarization have also been determined by polarization-electric field (P-E) hysteresis loop evaluation. On the basis of our experimental results, the phase transition and dielectric anisotropy in PIN-PMN-PT have been discussed.

引用

页数：16

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