New insights on the high-corrosion resistance of UHP Mg-Ge alloys tested in a simulated physiological environment

被引:6
作者
Liu, Ting [1 ]
Chen, Xingrui [1 ,2 ]
Venezuela, Jeffrey [1 ]
Wang, Yuan [1 ]
Shi, Zhiming [1 ]
Chen, Wenyi [1 ]
Dargusch, Matthew [1 ]
机构
[1] Univ Queensland, Ctr Adv Mat Proc & Mfg AMPAM, Sch Mech & Min Engn, Brisbane, Qld 4072, Australia
[2] CSIRO Mineral Resources, 1 Technol Court, Pullenvale, Qld 4069, Australia
关键词
UHP Mg-Ge alloy; Cathodic kinetics suppression; Biodegradable metals; In vitro corrosion; Magnesium corrosion; HIGH-PURITY MG; DIE-CAST MAGNESIUM; IN-VITRO; LOCALIZED CORROSION; MICROALLOYING ADDITIONS; DEGRADATION PERFORMANCE; MECHANICAL-PROPERTIES; HYDROGEN EVOLUTION; GRAIN-REFINEMENT; PURE MAGNESIUM;
D O I
10.1016/j.jma.2024.03.002
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
UHP Mg-Ge alloys was recently found to provide excellent corrosion resistance. This paper provides new insights on the mechanism of improved corrosion resistance of UHP Mg-Ge alloys in Hanks' solution. The studied UHP Mg-0.5Ge and UHP Mg-1Ge alloys showed superior corrosion resistance compared to UHP Mg and WE43, with the Mg-1Ge exhibiting the best corrosion performance. The exceptional corrosion resistance of the UHP alloy is attributed to (i) Mg2 Ge's ability to suppress cathodic kinetics, (ii) Ge's capability to accelerate the formation of a highly passive layer, and the (iii) low amounts of corrosion-accelerating impurities. (c) 2024 Chongqing University. Publishing services provided by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://creativecommons.org/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University
引用
收藏
页码:1026 / 1044
页数:19
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