Exploration of disodium methylenebis naphthalene sulfonatea as a novel depressant for the flotation separation of apatite from dolomite

被引:11
作者
Liu, Cheng [1 ,2 ,3 ,4 ]
Zhu, Yuhua [1 ]
Bao, Shenxu [1 ,2 ]
Ren, Liuyi [1 ,2 ]
Zhu, Yangge [1 ,3 ]
Xu, Wei [1 ,4 ]
Yang, Siyuan [1 ,2 ]
机构
[1] Wuhan Univ Technol, Sch Resources & Environm Engn, Wuhan 430070, Peoples R China
[2] Minist Educ, Key Lab Green Utilizat Crit Nonmet Mineral Resour, Wuhan 430070, Hubei, Peoples R China
[3] BGRIMM Technol Grp, State Key Lab Mineral Proc Sci & Technol, Beijing 102600, Peoples R China
[4] State Key Lab Efficient Utilizat Low Grade Phosph, Guiyang 550014, Peoples R China
基金
中国国家自然科学基金;
关键词
Apatite; Dolomite; DMNS depressant; Flotation separation; Adsorption mechanism; SEDIMENTARY PHOSPHATE ROCK; SELECTIVE FLOTATION; SILICATES; CARBONATE; IMPROVE; ACID; ORES;
D O I
10.1016/j.seppur.2024.126967
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
To address the flotation separation problem between apatite and dolomite, DMNS (disodium methylenebis naphthalene sulfonate) was selected as a depressant in this research. Micro-flotation results showed NaOl exhibited good floatability for dolomite and apatite, with no significant difference in the floatability between these two minerals. The addition of DMNS completely depressed the floatability of dolomite but slightly affected the floatability of apatite. The artificial minerals mixture flotation ensured that DMNS achieved the separation between apatite and dolomite when the NaOl was used. The adsorption measurement illustrated adsorption amount of DMNS on dolomite surface was more than that of it on apatite surface, the Zeta potential results illustrated NaOl still adsorbed on the apatite surface but did not adsorbed on the dolomite surface after conditioning with DMNS. XPS analysis verified that no effective interaction occurred between DMNS and apatite surface, and DMNS chemically adsorbed on the dolomite surface by the interaction between -SO3H groups of DMNS and Ca2+/Mg2+ of the dolomite surface. First-principles calculations further ensured the higher adsorption energy of DMNS on the dolomite surface. The computational calculation also revealed that the interaction of DMNS with the dolomite surface was much stronger than that with the apatite surface.
引用
收藏
页数:9
相关论文
共 49 条
[1]   Physical and thermal treatment of phosphate ores - An overview [J].
Abouzeid, Abdel-Zaher A. .
INTERNATIONAL JOURNAL OF MINERAL PROCESSING, 2008, 85 (04) :59-84
[2]  
[Anonymous], 1988, Flotation Solution Chemistry
[3]   Determination of mineral phosphate species in sedimentary phosphate rock in Mardin, SE Anatolia, Turkey by sequential extraction [J].
Aydin, Isil ;
Imamoglu, Sefik ;
Aydin, Firat ;
Saydut, Abdurrahman ;
Hamamci, Candan .
MICROCHEMICAL JOURNAL, 2009, 91 (01) :63-69
[4]   DFT simulations of pyrite galvanic interactions with bulk, solid-solution and nanoparticle Au occurrences - Insights into gold cyanidation [J].
Azizi, Dariush ;
Larachi, Faical .
MINERALS ENGINEERING, 2020, 149
[5]   A modification in the flotation process of a calcareous-siliceous phosphorite that might improve the process economics [J].
Boulos, Tawfik R. ;
Yehia, Ahmed ;
Ibrahim, Suzan S. ;
Yassin, Khaled E. .
MINERALS ENGINEERING, 2014, 69 :97-101
[6]   Structure and thermal stability of fluorhydroxyapatite and fluorapatite obtained by mechanochemical method [J].
Bulina, Natalia, V ;
Makarova, Svetlana, V ;
Prosanov, Igor Yu ;
Vinokurova, Olga B. ;
Lyakhov, Nikolay Z. .
JOURNAL OF SOLID STATE CHEMISTRY, 2020, 282
[7]   Chemical analysis of overbased calcium sulfonate detergents by coupling XPS, ToF-SIMS, XANES, and EFTEM [J].
Cizaire, L ;
Martin, JM ;
Le Mogne, T ;
Gresser, E .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2004, 238 (1-3) :151-158
[8]  
Coppola L., 2010, Journal of the Chinese Ceramic Society, V38, P1631
[9]   Linking the rise of atmospheric oxygen to growth in the continental phosphorus inventory [J].
Cox, Grant M. ;
Lyons, Timothy W. ;
Mitchell, Ross N. ;
Hasterok, Derrick ;
Gard, Matthew .
EARTH AND PLANETARY SCIENCE LETTERS, 2018, 489 :28-36
[10]   Fertiliser availability in a resource-limited world: Production and recycling of nitrogen and phosphorus [J].
Dawson, C. J. ;
Hilton, J. .
FOOD POLICY, 2011, 36 :S14-S22