Utilizing triethylenetetramine-functionalized MIP-206 for highly efficient removal of Pb(II) from wastewater

被引:5
作者
Shilani, Bizhan [1 ]
Mehdipour, Reza [1 ]
Mousazadeh, Behnam [2 ]
Noruzi, Yasin [3 ]
Hosseini, Seyednooroldin [1 ]
Al-Saedi, Hasan N. [4 ]
Mohealdeen, Sura Mohammad [5 ]
机构
[1] Islamic Azad Univ, EOR Res Ctr, Dept Petr Engn, Omidiyeh Branch, Omidiyeh, Iran
[2] Hetcochem Co, Res & Dev Dept, Tabriz, Iran
[3] Amirkabir Univ, Dept Petr Engn, Tehran, Iran
[4] Al Amarah Univ Collage, Dept Petr Engn, Missan, Iraq
[5] Al Noor Univ, Dept Radiol & Sonar Technol, Hlth & Med Tech Collage, Mosul, Iraq
关键词
Adsorption; Pb removal; Metal organic framework (MOF); MIP-206-OH; METAL-ORGANIC FRAMEWORK; ADSORPTIVE REMOVAL; IONS; ADSORBENT; CD(II);
D O I
10.1038/s41598-024-66358-6
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The global concern over heavy metal pollution necessitates urgent measures to safeguard human health and the environment. This study focuses on employing triethylenetetramine (TETA)-functionalized MIP-206-OH (TMIP-206) as an effective adsorbent for removing Pb(II) from wastewater. TMIP-206 was synthesized via a hydrothermal method followed by functionalization with TETA. Kinetic studies demonstrate that lead removal on TMIP-206 conforms to the pseudo-second-order model, indicating an efficient removal process. Experimental results reveal that TMIP-206 aligns with the Langmuir isotherm, exhibiting a maximum removal capacity of 267.15 mg/g for lead ions. The sorption efficiency of TMIP-206 for Pb ions remains stable across six cycles, with a reduction of less than 15%. Optimal adsorption performance is observed at a pH of 6. These findings underscore the potential of TMIP-206 as an alternative for adsorbing Pb(II) from aqueous environments, addressing the global challenge of heavy metal pollution. Future research should explore the scalability and long-term stability of TMIP-206-based adsorbents to enhance their practical applicability in diverse environmental contexts and contribute to broader strategies for mitigating heavy metal contamination.
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页数:13
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