Effect of urea on optical properties of potassium hydrogen phthalate (KHP) single crystals for NLO applications

被引:5
作者
Raju, R. K. [1 ]
Beena, P. [2 ]
Jayanna, H. S. [3 ]
机构
[1] Govt First Grade Coll, Dept Phys, Ripponpet 577426, Karnataka, India
[2] Govt First Grade Coll, Dept Phys, Tarikere 577228, Karnataka, India
[3] Kuvempu Univ, Dept Phys, Shankaraghatta 577451, Karnataka, India
来源
RESULTS IN OPTICS | 2023年 / 12卷
关键词
Lattice parameters; TG-DTA; Tauc plot; Second harmonic generation; ORGANIC DOPANTS; KDP CRYSTALS; GROWTH; IMPURITIES; ZTS; ENHANCEMENT; PERFECTION; NUCLEATION; KINETICS;
D O I
10.1016/j.rio.2023.100455
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Semi-organic carbamide (urea) doped potassium hydrogen phthalate (KHP) crystals grown from slow evaporation solution growth technique. The grown crystals were subjected to powder XRD analysis and doped KHP crystallizes in orthorhombic structure with space group Pca2(1). FTIR spectrum confirms the presence of major functional groups and shows minor distortion of functional groups due to effect of dopant. SEM studies revealed, the effectiveness urea dopant on surface morphology of grown crystals. From thermal studies, it is found that, both undoped and urea doped KHP were stable up to 300 C-degrees. UV-Visible studies showed, the grown crystals were transparent in the entire visible region and calculated optical band gap from Tauc's plots. The SHG studies of the grown crystals have been confirmed by Kurtz-Perry powder technique.
引用
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页数:6
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