Progress of In2O3-based catalysts in thermal catalytic CO2 hydrogenation reaction

被引：0
作者：
Jiao C.-X. [1 ]
Mu H.-M. [2 ]
Gao P. [1 ]
Yang X. [1 ]
Tian H.-F. [1 ]
Zha F. [1 ]
机构：
[1] Northwest Normal University Chemistry and Chemical Engineering, Lanzhou
[2] Lanzhou Resources & Environment Voc-Tech University, Lanzhou
来源：
Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2023年 / 51卷
基金：
中国国家自然科学基金;
关键词：
carbon dioxide; hydrocarbon compound; indium oxide; methanol;
D O I：
10.19906/j.cnki.JFCT.2022086
中图分类号：
学科分类号：
摘要：
Catalytic hydrogenation of CO2 is considered to be one of the most practical ways to produce value-added chemicals and fuels. However, due to the extreme chemical inertness, the high C–C coupling barrier and the many competing reactions, it is of vital important to develop the efficient catalysts for achieving the activation and transformation of CO2 into a variety of chemical products. In recent years, indium oxide has aroused great interest in CO2 hydrogenation due to its abundant oxygen vacancies, high selectivity of methanol and high activity of CO2 conversion. In this paper, the structure of In2O3 and the catalytic performance of In2O3-supported or metal-doped composite catalysts for CO2 hydrogenation to methanol are reviewed. The effects of the proximity of In2O3 to different zeolites and the migration of elements on the products of CO2 hydrogenation to hydrocarbons are also discussed. Finally, the challenges and development directions of selective hydrogenation of CO2 over In2O3-based catalysts are summarized. © 2023 Science Press. All rights reserved.
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页码：1701 / 1717
页数：16
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