Progress of In2O3-based catalysts in thermal catalytic CO2 hydrogenation reaction

被引：0

作者：

Jiao C.-X. ^{[1
]}

Mu H.-M. ^{[2
]}

Gao P. ^{[1
]}

Yang X. ^{[1
]}

Tian H.-F. ^{[1
]}

Zha F. ^{[1
]}

机构：

[1] Northwest Normal University Chemistry and Chemical Engineering, Lanzhou

[2] Lanzhou Resources & Environment Voc-Tech University, Lanzhou

来源：

Ranliao Huaxue Xuebao/Journal of Fuel Chemistry and Technology | 2023年 / 51卷

基金：

中国国家自然科学基金;

关键词：

carbon dioxide; hydrocarbon compound; indium oxide; methanol;

D O I：

10.19906/j.cnki.JFCT.2022086

中图分类号：

学科分类号：

摘要：

Catalytic hydrogenation of CO2 is considered to be one of the most practical ways to produce value-added chemicals and fuels. However, due to the extreme chemical inertness, the high C–C coupling barrier and the many competing reactions, it is of vital important to develop the efficient catalysts for achieving the activation and transformation of CO2 into a variety of chemical products. In recent years, indium oxide has aroused great interest in CO2 hydrogenation due to its abundant oxygen vacancies, high selectivity of methanol and high activity of CO2 conversion. In this paper, the structure of In2O3 and the catalytic performance of In2O3-supported or metal-doped composite catalysts for CO2 hydrogenation to methanol are reviewed. The effects of the proximity of In2O3 to different zeolites and the migration of elements on the products of CO2 hydrogenation to hydrocarbons are also discussed. Finally, the challenges and development directions of selective hydrogenation of CO2 over In2O3-based catalysts are summarized. © 2023 Science Press. All rights reserved.

引用

页码：1701 / 1717

页数：16

共 80 条

[1]

WANG Han, FAN Sheng, WANG Sen, DONG Mei, QIN Zhang-feng, FAN Wei-bin, WANG Jian-guo, Research progresses in the hydrogenation of carbon dioxide to certain hydrocarbon products[J], J Fuel Chem Technol, 49, 11, pp. 1609-1619, (2021)

[2]

EBI K L., Key themes in the working group II contribution to the intergovernmental panel on climate change 5th assessment report[J], Clim Change, 114, 3, (2012)

[3]

PECHENKIN A, POTEMKIN D, BADMAEV S, SMIRNOVA E, CHEREDNICHENKO K, VINOKUROV V, GLOTOV A., CO2 hydrogenation to dimethyl ether over In2O3 catalysts supported on aluminosilicate halloysite nanotubes[J], Green Process Synth, 10, 1, pp. 594-605, (2021)

[4]

NOCITO F, DIBENEDETTO A., Atmospheric CO2 mitigation technologies: carbon capture utilization and storage[J], Current Opinion Green Sustainable Chem, 21, pp. 34-43, (2020)

[5]

MEYLAN F D, MOREAU V, ERKMAN S., CO2 utilization in the perspective of industrial ecology, an overview[J], J CO2 Util, 12, (2015)

[6]

NIE X W, LI W H, JIANG X, GUO X W, SONG C S., Recent advances in catalytic CO2 hydrogenation to alcohols and hydrocarbons[J], Adv Catal, 65, pp. 121-233, (2019)

[7]

POROSOFF M D, YAN B, CHEN J G., Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: Challenges and opportunities[J], Energy Environ Sci, 9, 1, (2016)

[8]

BANERJEE A, DICK G R, YOSHINO T, KANAN M W., Carbon dioxide utilization via carbonate-promoted C–H carboxylation[J], Nature, 531, 7593, pp. 215-219, (2016)

[9]

ZHOU C, SHI J Q, ZHOU W, CHENG K, ZHANG Q Q, KANG J C, WANG Y., Highly active ZnO-ZrO2 aerogels integrated with H-ZSM-5 for aromatics synthesis from carbon dioxide[J], ACS Catal, 10, 1, (2019)

[10]

POROSOFF M D, YANG X F, BOSCOBOINIK J A, CHEN J G G., Molybdenum carbide as alternative catalysts to precious metals for highly selective reduction of CO2 to CO[J], Angew Chem Int Ed, 53, 26, pp. 6705-6709, (2014)

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