SYNTHESIS AND STRUCTURE OF A COPPER(II) COMPLEX BASED ON N-2-(2-PYRIDYL)ETHYL-2-AMINOETHANESULFONIC ACID

被引：0
作者：
Zemlyakova, E. O. [2 ]
Zharkov, G. P. [1 ]
Petrova, Y. S. [1 ]
Neudachina, L. K. [1 ]
Slepukhin, P. A. [2 ]
Aksenova, T. V. [1 ]
Pestov, A. V. [1 ,2 ]
机构：
[1] Ural Fed Univ, Ekaterinburg, Russia
[2] Russian Acad Sci, Ural Branch, Postovsky Inst Organ Synth, Ekaterinburg, Russia
来源：
JOURNAL OF STRUCTURAL CHEMISTRY | 2024年 / 65卷 / 07期
关键词：
copper(II) complexes; taurine N-derivatives; complexation; CRYSTAL-STRUCTURES; EFFICIENT LIGAND; CARBOXYLATE; SULFONATE; CATALYST;
D O I：
10.1134/S0022476624070102
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel copper(II) complex based on N-2-(2-pyridyl)ethyl-2-aminoethanesulfonic acid is prepared, its structure is studied by XRD (CCDC No. 2215117). The crystal of the complex is formed by monomeric [CuLH2O]NO3 units. The metal centers of the units have an octahedral coordination environment formed by nitrogen atoms of pyridine and the amino group, oxygen atoms of the sulfo group, and water molecules located in the equatorial plane. On the axial axis, there are oxygen atoms of the sulfo groups of the neighboring ligands forming a 1D coordination polymer.
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收藏
页码：1395 / 1403
页数：9
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  • [1] Synthesis of β-aminoacid derivatives via kenantioselective hydrogenation of β-substituted-β-(acylamino)acrylates
    Bruneau, Christian
    Renaud, Jean-Luc
    Jerphagnon, Thomas
    [J]. COORDINATION CHEMISTRY REVIEWS, 2008, 252 (5-7) : 532 - 544
  • [2] Tetracopper(II) Cores Driven by an Unexplored Trifunctional Aminoalcohol Sulfonic Acid for Mild Catalytic C-H Functionalization of Alkanes
    Costa, Ines F. M.
    Kirillova, Marina V.
    Andre, Vania
    Fernandes, Tiago A.
    Kirillov, Alexander M.
    [J]. CATALYSTS, 2019, 9 (04):
  • [3] New Tetracopper(II) Cubane Cores Driven by a Diamino Alcohol: Self-assembly Synthesis, Structural and Topological Features, and Magnetic and Catalytic Oxidation Properties
    Dias, Sara S. P.
    Kirillova, Marina V.
    Andre, Vania
    Klak, Julia
    Kirillov, Alexander M.
    [J]. INORGANIC CHEMISTRY, 2015, 54 (11) : 5204 - 5212
  • [4] Di-μ-chlorido-bis{[2-(2-pyridylmethylamino)ethanesulfonato-κ3N,N′,O]-copper(II)}
    Du, Zhong-Xiang
    Qin, Jian-Hua
    Wang, Jian-Ge
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M341 - U640
  • [5] Anion influences on the structures of pyridyl-iminosulfonate copper(II) complexes and their reactivity in Chan-Lam couplings
    Duparc, Valerie Hardouin
    Thouvenin, Alexandre
    Schaper, Frank
    [J]. CANADIAN JOURNAL OF CHEMISTRY, 2020, 98 (09) : 502 - 510
  • [6] Using coordination chemistry to develop new routes to semiconductor and other materials
    Fan, Dongbo
    Afzaal, Mohammad
    Mallik, M. Azad
    Nguyen, Chinh Q.
    O'Brien, Paul
    Thomas, P. John
    [J]. COORDINATION CHEMISTRY REVIEWS, 2007, 251 (13-14) : 1878 - 1888
  • [7] Transition-Metal Complexes Based on a Sulfonate-Containing N-Donor Ligand and Their Use as HIV Antiviral Agents
    Garcia-Gallego, Sandra
    Jesus Serramia, M.
    Arnaiz, Eduardo
    Diaz, Laura
    Angeles Munoz-Fernandez, M.
    Gomez-Sal, Pilar
    Francesca Ottaviani, M.
    Gomez, Rafael
    Javier de la Mata, F.
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (10) : 1657 - 1665
  • [8] Principles of mononucleating and binucleating ligand design
    Gavrilova, AL
    Bosnich, B
    [J]. CHEMICAL REVIEWS, 2004, 104 (02) : 349 - 383
  • [9] Bringing an "Old" Biological Buffer to Coordination Chemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for Mild Hydrocarboxylation of Alkanes
    Kirillov, Alexander M.
    Coelho, Jaime A. S.
    Kirillova, Marina V.
    da Silva, M. Fatima C. Guedes
    Nesterov, Dmytro S.
    Gruenwald, Katrin R.
    Haukka, Matti
    Pombeiro, Armando J. L.
    [J]. INORGANIC CHEMISTRY, 2010, 49 (14) : 6390 - 6392
  • [10] Topologically Unique Heterometallic CuII/Li Coordination Polymers Self-Assembled from N,N-bis(2-Hydroxyethyl)-2-aminoethanesulfonic Acid Biobuffer: Versatile Catalyst Precursors for Mild Hydrocarboxylation of Alkanes to Carboxylic Acids
    Kirillova, Marina V.
    Kirillov, Alexander M.
    Martins, Andre N. C.
    Graiff, Claudia
    Tiripicchio, Antonio
    Pombeiro, Armando J. L.
    [J]. INORGANIC CHEMISTRY, 2012, 51 (09) : 5224 - 5234
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