A high-temperature anion-exchange membrane fuel cell with a critical raw material-free cathode

被引：0
|
作者：
Douglin, John C. [1 ]
Singh, Ramesh K. [1 ,2 ]
Haj-Bsoul, Saja [1 ]
Li, Songlin [1 ]
Biemolt, Jasper [3 ]
Yan, Ning [3 ]
Varcoe, John R. [4 ]
Rothenberg, Gadi [3 ]
Dekel, Dario R. [1 ,2 ]
机构：
[1] Technion Israel Inst Technol, Wolfson Dept Chem Engn, IL-3200003 Haifa, Israel
[2] Technion Israel Inst Technol, Nancy & Stephen Grand Technion Energy Program GTEP, IL-3200003 Haifa, Israel
[3] Univ Amsterdam, Van tHoff Inst Mol Sci, Sci Pk 904, NL-1098 XH Amsterdam, Netherlands
[4] Univ Surrey, Dept Chem, Guildford GU2 7XH, England
来源：
CHEMICAL ENGINEERING JOURNAL ADVANCES | 2021年 / 8卷
基金：
英国工程与自然科学研究理事会;
关键词：
Anion-exchange membrane fuel cells; HT-AEMFC; Critical raw materials-free; PGM-free; oxygen reduction reaction; N-doped-C; OXYGEN REDUCTION; HYDROXIDE CONDUCTIVITY; FREE CATALYSTS; ALKALINE; ELECTROCATALYSTS; STABILITY; SITES;
D O I：
暂无
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
We present a first high-temperature anion-exchange membrane fuel cell (HT-AEMFC, operating at 105 degrees C) based on a critical raw material (CRM)-free cathode catalyst; at the same temperature, the anion-exchange membrane (AEM) has a high ex-situ hydroxide conductivity value of 201 mS cm-1. Our HT-AEMFC, containing a highly active nitrogen-doped carbon (N-doped-C) cathode catalyst, also features low polarization resistances, high catalytic activity and stability, with retention of 81% of the catalyst layer capacitance after an initial 10 h longevity test, and delivery of a peak power of 1.14 W cm-2. This is one of the highest power densities reported for an AEMFC containing a CRM-free cathode. This work shows the potential of the new field of HT-AEMFCs, opening opportunities for developing and using novel CRM-free catalysts that are highly active at these high operating temperatures.
引用
收藏
页数：6
相关论文
共 50 条
  • [21] A high-performance integrated electrode for anion-exchange membrane direct ethanol fuel cells
    Li, Y. S.
    Zhao, T. S.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (13) : 7707 - 7713
  • [22] Transition-Metal and Nitrogen-Doped Carbon Nanotube/Graphene Composites as Cathode Catalysts for Anion-Exchange Membrane Fuel Cells
    Lilloja, Jaana
    Kibena-Poldsepp, Elo
    Sarapuu, Ave
    Konovalova, Anastasiia
    Kaarik, Maike
    Kozlova, Jekaterina
    Paiste, Paarn
    Kikas, Arvo
    Treshchalov, Alexey
    Aruvali, Jaan
    Zitolo, Andrea
    Leis, Jaan
    Tamm, Aile
    Kisand, Vambola
    Holdcroft, Steven
    Tammeveski, Kaido
    ACS APPLIED ENERGY MATERIALS, 2023, 6 (10) : 5519 - 5529
  • [23] Mesoporous iron-nitrogen co-doped carbon material as cathode catalyst for the anion exchange membrane fuel cell
    Lilloja, Jaana
    Mooste, Marek
    Kibena-Poldsepp, Elo
    Sarapuu, Ave
    Zulevi, Barr
    Kikas, Arvo
    Piirsoo, Helle-Mai
    Tamm, Aile
    Kisand, Vambola
    Holdcroft, Steven
    Serov, Alexey
    Tammeveski, Kaido
    JOURNAL OF POWER SOURCES ADVANCES, 2021, 8
  • [24] Plasma-Assisted Synthesis of Metal Nitrides for an Efficient Platinum-Group-Metal-Free Anion-Exchange-Membrane Fuel Cell
    Zhang, Xiao-Long
    Hu, Shao-Jin
    Wang, Ye-Hua
    Shi, Lei
    Yang, Yu
    Gao, Min-Rui
    NANO LETTERS, 2023, 23 (01) : 107 - 115
  • [25] Polypyrrole and Polythiophene Modified Carbon Nanotube-Based Cathode Catalysts for Anion Exchange Membrane Fuel Cell
    Sokka, Andri
    Mooste, Marek
    Marandi, Margus
    Kaarik, Maike
    Kozlova, Jekaterina
    Kikas, Arvo
    Kisand, Vambola
    Treshchalov, Alexey
    Tamm, Aile
    Leis, Jaan
    Holdcroft, Steven
    Tammeveski, Kaido
    CHEMELECTROCHEM, 2022, 9 (07)
  • [26] Lignin-Derived Precious Metal-Free Electrocatalysts for Anion-Exchange Membrane Fuel Cell Application
    Sajjad, Umber
    Sarapuu, Ave
    Douglin, John C.
    Kikas, Arvo
    Treshchalov, Alexey
    Kaarik, Maike
    Kozlova, Jekaterina
    Aruvali, Jaan
    Leis, Jaan
    Kisand, Vambola
    Kukli, Kaupo
    Dekel, Dario R.
    Tammeveski, Kaido
    ACS CATALYSIS, 2024, : 9224 - 9234
  • [27] Recent trends on the application of PGM-free catalysts at the cathode of anion exchange membrane fuel cells
    Osmieri, Luigi
    Pezzolato, Lorenzo
    Specchia, Stefania
    CURRENT OPINION IN ELECTROCHEMISTRY, 2018, 9 : 240 - 256
  • [28] Nitrogen and sulphur co-doped carbon-based composites as electrocatalysts for the anion-exchange membrane fuel cell cathode
    Palm, Iris
    Kibena-Poldsepp, Elo
    Mooste, Marek
    Kozlova, Jekaterina
    Kaarik, Maike
    Kikas, Arvo
    Treshchalov, Alexey
    Leis, Jaan
    Kisand, Vambola
    Tamm, Aile
    Holdcroft, Steven
    Tammeveski, Kaido
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2024, 55 : 805 - 814
  • [29] Ionothermal synthesis of mesoporous FeNC electrocatalysts for high-performance anion-exchange membrane fuel cells
    Ibrahim, Faruq Olamilekan
    Kisand, Kaarel
    Douglin, John C.
    Sarapuu, Ave
    Kikas, Arvo
    Kaarik, Maike
    Kozlova, Jekaterina
    Aruvali, Jaan
    Treshchalov, Alexey
    Leis, Jaan
    Kisand, Vambola
    Kukli, Kaupo
    Yassin, Karam
    Dekel, Dario R.
    Tammeveski, Kaido
    CHEMICAL ENGINEERING JOURNAL, 2025, 510
  • [30] Review: chitosan-based biopolymers for anion-exchange membrane fuel cell application
    Myrzakhmetov, Bauyrzhan
    Akhmetova, Aktilek
    Bissenbay, Aiman
    Karibayev, Mirat
    Pan, Xuemiao
    Wang, Yanwei
    Bakenov, Zhumabay
    Mentbayeva, Almagul
    ROYAL SOCIETY OPEN SCIENCE, 2023, 10 (11):
12345