Enantioselective iron-catalysed transformations. An update

被引:1
作者
Pellissier, Helene [1 ]
机构
[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2, Marseille, France
关键词
Asymmetric iron catalysis; Enantioselective reactions; Metal catalysis; Chirality; Asymmetric catalysis; DOMINO REACTIONS; MULTICOMPONENT REACTIONS; ALPHA; BETA-UNSATURATED KETONES; ASYMMETRIC OXIDATION; CHIRAL SULFOXIDES; ORGANIC-SYNTHESIS; TANDEM; METAL; COMPLEXES; CASCADE;
D O I
10.1016/j.tet.2024.133944
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review updates the field of enantioselective iron-catalysed transformations of all types since the beginning of 2020. It shows that asymmetric iron catalysis, that suits the growing demand for greener processes, offers a real opportunity to replace toxic and expensive metals in the near future. The review includes enantioselective ironcatalysed domino reactions; reductions of ketones and imines; cycloadditions; additions to alkenes; coupling reactions; Michael-type reactions; alpha-functionalisations of carbonyl compounds; sulfoxidations; alkylations of indoles; rearrangement reactions; intramolecular aminations; and miscellaneous reactions.
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页数:30
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共 157 条
  • [51] Pot economy and one-pot synthesis
    Hayashi, Yujiro
    [J]. CHEMICAL SCIENCE, 2016, 7 (02) : 866 - 880
  • [52] Asymmetric catalytic nitrooxylation and azidation of β-keto amides/esters with hypervalent iodine reagents
    He, Changqiang
    Wu, Zhikun
    Zhou, Yuqiao
    Cao, Weidi
    Feng, Xiaoming
    [J]. ORGANIC CHEMISTRY FRONTIERS, 2022, 9 (03): : 703 - 708
  • [53] Herrera RP, 2015, Multicomponent Reactions: Concepts and Applications for Design and Synthesis, P1, DOI 10.1002/9781118863992
  • [54] Ho T.-L., 1992, TANDEM ORGANIC REACT, DOI DOI 10.1021/ja7100449
  • [55] Chiral-at-Iron Catalyst for Highly Enantioselective and Diastereoselective Hetero-Diels-Alder Reaction
    Hong, Yubiao
    Cui, Tianjiao
    Ivlev, Sergei
    Xie, Xiulan
    Meggers, Eric
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2021, 27 (33) : 8557 - 8563
  • [56] MULTIMACROCYCLIC COMPOUNDS .4. INTERNAL TRIMERISATION OF TRIPLE BONDS OF LINEAR TRIYNES ON A ZIEGLER CATALYST
    HUBERT, AJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1967, (20): : 1984 - &
  • [57] Multi-component reactions : Emerging chemistry in drug discovery 'From xylocain to crixivan'
    Hulme, C
    Gore, V
    [J]. CURRENT MEDICINAL CHEMISTRY, 2003, 10 (01) : 51 - 80
  • [58] An iron variant of the Noyori hydrogenation catalyst for the asymmetric transfer hydrogenation of ketones
    Huo, Shangfei
    Wang, Qingwei
    Zuo, Weiwei
    [J]. DALTON TRANSACTIONS, 2020, 49 (23) : 7959 - 7967
  • [59] Johnson J., 2011, Science of Synthesis, Stereoselective Synthesis, P759
  • [60] Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts
    Kaiser, Daniel
    Klose, Immo
    Oost, Rik
    Neuhaus, James
    Maulide, Nuno
    [J]. CHEMICAL REVIEWS, 2019, 119 (14) : 8701 - 8780