Enantioselective iron-catalysed transformations. An update

被引:1
作者
Pellissier, Helene [1 ]
机构
[1] Aix Marseille Univ, CNRS, Cent Marseille, iSm2, Marseille, France
关键词
Asymmetric iron catalysis; Enantioselective reactions; Metal catalysis; Chirality; Asymmetric catalysis; DOMINO REACTIONS; MULTICOMPONENT REACTIONS; ALPHA; BETA-UNSATURATED KETONES; ASYMMETRIC OXIDATION; CHIRAL SULFOXIDES; ORGANIC-SYNTHESIS; TANDEM; METAL; COMPLEXES; CASCADE;
D O I
10.1016/j.tet.2024.133944
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review updates the field of enantioselective iron-catalysed transformations of all types since the beginning of 2020. It shows that asymmetric iron catalysis, that suits the growing demand for greener processes, offers a real opportunity to replace toxic and expensive metals in the near future. The review includes enantioselective ironcatalysed domino reactions; reductions of ketones and imines; cycloadditions; additions to alkenes; coupling reactions; Michael-type reactions; alpha-functionalisations of carbonyl compounds; sulfoxidations; alkylations of indoles; rearrangement reactions; intramolecular aminations; and miscellaneous reactions.
引用
收藏
页数:30
相关论文
共 157 条
  • [11] TacklingN-Alkyl Imines with 3d Metal Catalysis: Highly Enantioselective Iron-Catalyzed Synthesis of α-Chiral Amines
    Blasius, Clemens K.
    Heinrich, Niklas F.
    Vasilenko, Vladislav
    Gade, Lutz H.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (37) : 15974 - 15977
  • [12] Iron-catalyzed reactions in organic synthesis
    Bolm, C
    Legros, J
    Le Paih, J
    Zani, L
    [J]. CHEMICAL REVIEWS, 2004, 104 (12) : 6217 - 6254
  • [13] A new iron age
    Bolm, Carsten
    [J]. NATURE CHEMISTRY, 2009, 1 (05) : 420 - 420
  • [14] Crossed Regio- and Enantioselective Iron-Catalyzed [4+2]-Cycloadditions of Unactivated Dienes
    Braconi, Elena
    Cramer, Nicolai
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (07)
  • [15] Enantioselective Iron-Catalyzed Cross-[4+4]-Cycloaddition of 1,3-Dienes Provides Chiral Cyclooctadienes
    Braconi, Elena
    Gotzinger, Alissa C.
    Cramer, Nicolai
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (47) : 19819 - 19824
  • [16] Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2
    Bryliakov, Konstantin P.
    [J]. CHEMICAL REVIEWS, 2017, 117 (17) : 11406 - 11459
  • [17] RECENT ADVANCES IN THE USE OF TANDEM REACTIONS FOR ORGANIC-SYNTHESIS
    BUNCE, RA
    [J]. TETRAHEDRON, 1995, 51 (48) : 13103 - 13159
  • [18] Enantiopure sulfoxides: recent applications in asymmetric synthesis
    Carmen Carreno, M.
    Hernandez-Torres, Gloria
    Ribagorda, Maria
    Urbano, Antonio
    [J]. CHEMICAL COMMUNICATIONS, 2009, (41) : 6129 - 6144
  • [19] APPLICATIONS OF SULFOXIDES TO ASYMMETRIC-SYNTHESIS OF BIOLOGICALLY-ACTIVE COMPOUNDS
    CARRENO, MC
    [J]. CHEMICAL REVIEWS, 1995, 95 (06) : 1717 - 1760
  • [20] Recent Advances in Asymmetric Iron Catalysis
    Casnati, Alessandra
    Lanzi, Matteo
    Cera, Gianpiero
    [J]. MOLECULES, 2020, 25 (17):