Highly sensitive and efficient hydrazine sensor probe development based onMoO3/CuO/ZnO ternarymixed metal oxide nano-composites for sustainable environment

被引:0
作者
Subhan, Md Abdus [1 ]
Saha, Pallab Chandra [1 ]
Akand, Mohammad Arifur Rahman [1 ]
Asiri, Abdullah M. [2 ]
Al-Mamun, Mohammad [3 ]
Rahman, Mohammed M. [2 ]
机构
[1] Shah Jalal Univ Sci & Technol, Dept Chem, Sylhet 3114, Bangladesh
[2] King Abdulaziz Univ, Dept Chem, Ctr Excellence Adv Mat Res CEAMR, Fac Sci, Jeddah, Saudi Arabia
[3] Griffith Univ, Ctr Clean Environm & Energy, Griffith Sch Environm, Gold Coast Campus, Griffith, NSW, Australia
来源
ELECTROCHEMICAL SCIENCE ADVANCES | 2022年 / 2卷 / 01期
关键词
electro-chemical method; environmental safety; fabrication; hydrazine detection; MoO3/CuO/; ZnO nanomaterials; GLASSY-CARBON ELECTRODE; ELECTROCATALYTIC OXIDATION; CHEMICAL SENSOR; NANOPARTICLES; FABRICATION; PERFORMANCE; NANOSHEETS; PHOTOCATALYSIS; FLUORESCENT; NANOTUBES;
D O I
10.1002/elsa.202100031
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, by using a co-precipitationmethodMoO(3)/CuO/ZnO nanocomposite material was synthesized. Then the prepared material was fully characterized by using XRD (X-ray diffraction), SEM (scanning electron microscopy), EDS (energy dispersive x-ray spectroscopy), CV (cyclic voltammetry), and EIS (Electrochemical Impedance Spectroscopy). Zeta potential and hydrodynamic size were measured using a Zetasizer in PBS buffer. By using Scherrer's formula from XRD, particle size was determined which was around 26.5 nm. For the promising chemical sensor development, MoO3/CuO/ZnO nanocomposite material was fabricated onto a glassy carbon electrode (GCE) to provide a sensor probe with a fast response towards the selective hydrazine (HZ) toxin in phosphate buffer phase. The fabricated sensor probe is exhibited good sensitivity and long-term stability as well as enhanced electrochemical performances. A calibration plot was found linear in the range of 0.2nMto 2.0mM(linear dynamic range, LDR) in presence of aqueous HZ solutions with highest sensitivity value and lower limit of detection and good limit of quantification (LOQ). This approach is promising as an efficient technique in developing a highly effective sensor probe with ternary metal oxides for detecting environmental pollutants on a broad scale.
引用
收藏
页数:13
相关论文
共 75 条
  • [1] Low temperature chemical synthesis and comparative studies of silver oxide nanoparticles
    Ahmad, Tokeer
    Wani, Irshad A.
    Al-Hartomy, Omar A.
    Al-Shihri, Ayed S.
    Kalam, Abul
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2015, 1084 : 9 - 15
  • [2] Electrocatalytic Oxidation of 4-Aminophenol Molecules at the Surface of an FeS2/Carbon Nanotube Modified Glassy Carbon Electrode in Aqueous Medium
    Ahmed, Jahir
    Rakib, Riad H.
    Rahman, Mohammed M.
    Asiri, Abdullah M.
    Siddiquey, Iqbal A.
    Islam, Saiful S. M.
    Hasnat, Mohammad A.
    [J]. CHEMPLUSCHEM, 2019, 84 (02): : 175 - 182
  • [3] Efficient Bisphenol-A detection based on the ternary metal oxide (TMO) composite by electrochemical approaches
    Ahmed, Jahir
    Rahman, Mohammed M.
    Siddiquey, Iqbal A.
    Asiri, Abdullah M.
    Hasnat, Mohammad A.
    [J]. ELECTROCHIMICA ACTA, 2017, 246 : 597 - 605
  • [4] Fabrication of sensitive D-fructose sensor based on facile ternary mixed ZnO/CdO/SnO2 nanocomposites by electrochemical approach
    Alam, M. M.
    Asiri, Abdullah M.
    Rahman, Mohammed M.
    Islam, M. A.
    [J]. SURFACES AND INTERFACES, 2020, 19
  • [5] Insights of temperature dependent catalysis and kinetics of electro-oxidation of nitrite ions on a glassy carbon electrode
    Alam, Md Saiful
    Rahman, Mohammed M.
    Marwani, Hadi M.
    Hasnat, Mohammad A.
    [J]. ELECTROCHIMICA ACTA, 2020, 362 (362)
  • [6] Enhanced electrocatalytic effects of Pd particles immobilized on GC surface on the nitrite oxidation reactions
    Alam, Md. Saiful
    Shabik, Md. Fazle
    Rahman, Mohammed M.
    del Valle, Manel
    Hasnat, Mohammad A.
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2019, 839 : 1 - 8
  • [8] Assessment of enhanced nitrite removal and monitoring using ligand modified stable conjugate materials
    Awual, Md. Rabiul
    Asiri, Abdullah M.
    Rahman, Mohammed M.
    Alharthi, Nabeel H.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2019, 363 : 64 - 72
  • [9] Determination of hydrazine by polyNi(II) complex modified electrodes with a wide linear calibration range
    Azad, Uday Pratap
    Ganesan, Vellaichamy
    [J]. ELECTROCHIMICA ACTA, 2011, 56 (16) : 5766 - 5770
  • [10] B-McAuley C., 2006, Analyst., V131, P106