Chiral P,N,N-Ligands for Asymmetric Hydrogenation

被引：9

作者：

Liang, Ding-Hua ^{[1
]}

Hou, Chuan-Jin ^{[1
]}

Li, Qi ^{[1
]}

Qin, Hao ^{[1
]}

Li, Ling ^{[1
]}

Hu, Xiang-Ping ^{[2
]}

机构：

[1] Dalian Polytech Univ, Sch Light Ind & Chem Engn, Dalian 116034, Peoples R China

[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2024年 / 366卷 / 10期

关键词：

Asymmetric catalysis; Chiral ligands; Hydrogenation; P; N; N-ligands; LIGAND BIFUNCTIONAL CATALYSIS; BETA-KETO-ESTERS; ENANTIOSELECTIVE HYDROGENATION; TRIDENTATE LIGANDS; IRIDIUM CATALYSTS; 1,2-AMINO ALCOHOLS; EFFICIENT ACCESS; GROUP LEADS; COMPLEXES; MECHANISM;

D O I：

10.1002/adsc.202400092

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The chiral P,N,N-ligands represented a new type of tridentate ligand developed in recent years and displayed wide utilities in asymmetric catalysis. In the past decades, numerous chiral P,N,N-ligands with ferrocene, phenethylamine and spiro backbones were synthesized by addition of an aminopyridine, imidazole or diamines coordinating group. These chiral tridentate P,N,N-ligands showed excellent performance in the ruthenium, iridium, manganese, or cobalt-catalyzed asymmetric hydrogenations. A wide range of substrates, including simple ketones, alpha-halogenated ketones, alpha-hydroxy ketones, alpha- or beta-amino keto- ones, alpha-, gamma-, or delta-keto acids, alpha- or beta-keto amides, beta- or delta-keto esters, alpha- or beta-enones, olefins, imines, quinolines and indoles, could be hydrogenated to afford the corresponding chiral products with high yields and enantioselectivities. In this review, progress on the asymmetric hydrogenation of C=O, C=N, C=C bonds with chiral tridentate P,N,N-ligands was summarized. image

引用

页码：2165 / 2185

页数：21

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