Engineering transition metal-based nanomaterials for high-performance electrocatalysis

被引：41

作者：

Wang, Changhong ^{[1
]}

Li, Changming ^{[1
,2
,3
]}

Liu, Jinlong ^{[4
]}

Guo, Chunxian ^{[1
]}

机构：

[1] Suzhou Univ Sci & Technol, Sch Mat Sci & Engn, Inst Mat Sci & Devices, Suzhou 215009, Jiangsu, Peoples R China

[2] Jiangsu Key Lab Micro & Nano Heat Fluid Flow Techn, Suzhou 215009, Peoples R China

[3] Southwest Univ, Inst Clean Energy & Adv Mat, Chongqing 400715, Peoples R China

[4] Univ Auckland, Sch Chem Sci, Auckland 1142, New Zealand

来源：

MATERIALS REPORTS: ENERGY | 2021年 / 1卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Transition metal; Nanomaterials; Electrocatalysis; Hydrogen evolution reaction; Oxygen evolution reaction; CO2 reduction reaction; Nitrate reduction reaction; Engineering strategy; HYDROGEN EVOLUTION; ALLOY NANOPARTICLES; ORGANIC FRAMEWORK; RATIONAL DESIGN; CARBON; CATALYSTS; SINGLE; NANOCRYSTALS; REDUCTION; CO2;

D O I：

10.1016/j.matre.2021.01.001

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition metal (TM) based electrocatalysts attract increasing attention in energy conversion reactions, and current effects focus on material engineering strategies to tailor physicochemical properties of TM based electrocatalysts for improved performance. This review provides a summary about the recent advances of engineering TM based nanomaterials for electrocatalytic reactions, which include hydrogen evolution reaction (HER), oxygen evolution reaction (OER), CO2 reduction reaction (CO2RR), and nitrate reduction reaction (NO3-RR). We highlight four engineering strategies, namely, size engineering, facet engineering, composition engineering, and crystal structure engineering for TM based electrocatalysts, and pay a special emphasis on exploring the relationship between their physicochemical properties and catalytic activities. We outline the opportunities in this research field, in particular, the strategy of rationally combining in-situ and operando techniques and theoretical predication to design efficient electrocatalysts. Finally, issues that deserve attention and consideration for practical applications are discussed.

引用

页数：14

共 61 条

[1] Global patterns of nitrate storage in the vadose zone [J].

Ascott, M. J. ;

Gooddy, D. C. ;

Wang, L. ;

Stuart, M. E. ;

Lewis, M. A. ;

Ward, R. S. ;

Binley, A. M. .

NATURE COMMUNICATIONS, 2017, 8

[2] Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels [J].

Birdja, Yuvraj Y. ;

Perez-Gallent, Elena ;

Figueiredo, Marta C. ;

Gottle, Adrien J. ;

Calle-Vallejo, Federico ;

Koper, Marc T. M. .

NATURE ENERGY, 2019, 4 (09) :732-745

[3] The Evolution and Future of Earth's Nitrogen Cycle [J].

Canfield, Donald E. ;

Glazer, Alexander N. ;

Falkowski, Paul G. .

SCIENCE, 2010, 330 (6001) :192-196

[4] Platinum-nickel alloy excavated nano-multipods with hexagonal close-packed structure and superior activity towards hydrogen evolution reaction [J].

Cao, Zhenming ;

Chen, Qiaoli ;

Zhang, Jiawei ;

Li, Huiqi ;

Jiang, Yaqi ;

Shen, Shouyu ;

Fu, Gang ;

Lu, Bang-an ;

Xie, Zhaoxiong ;

Zheng, Lansun .

NATURE COMMUNICATIONS, 2017, 8 :15131

[5] Beyond fossil fuel-driven nitrogen transformations [J].

Chen, Jingguang G. ;

Crooks, Richard M. ;

Seefeldt, Lance C. ;

Bren, Kara L. ;

Bullock, R. Morris ;

Darensbourg, Marcetta Y. ;

Holland, Patrick L. ;

Hoffman, Brian ;

Janik, Michael J. ;

Jones, Anne K. ;

Kanatzidis, Mercouri G. ;

King, Paul ;

Lancaster, Kyle M. ;

Lymar, Sergei V. ;

Pfromm, Peter ;

Schneider, William F. ;

Schrock, Richard R. .

SCIENCE, 2018, 360 (6391)

[6] Well-faceted noble-metal nanocrystals with nonconvex polyhedral shapes [J].

Chen, Qiaoli ;

Jia, Yanyan ;

Xie, Shuifen ;

Xie, Zhaoxiong .

CHEMICAL SOCIETY REVIEWS, 2016, 45 (11) :3207-3220

[7] Syntheses and Properties of Metal Nanomaterials with Novel Crystal Phases [J].

Cheng, Hongfei ;

Yang, Nailiang ;

Lu, Qipeng ;

Zhang, Zhicheng ;

Zhang, Hua .

ADVANCED MATERIALS, 2018, 30 (26)

[8] Platinum single-atom and cluster catalysis of the hydrogen evolution reaction [J].

Cheng, Niancai ;

Stambula, Samantha ;

Wang, Da ;

Banis, Mohammad Norouzi ;

Liu, Jian ;

Riese, Adam ;

Xiao, Biwei ;

Li, Ruying ;

Sham, Tsun-Kong ;

Liu, Li-Min ;

Botton, Gianluigi A. ;

Sun, Xueliang .

NATURE COMMUNICATIONS, 2016, 7

[9] A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions [J].

Cui, Xiaoyang ;

Tang, Cheng ;

Zhang, Qiang .

ADVANCED ENERGY MATERIALS, 2018, 8 (22)

[10] Robust Catalysis on 2D Materials Encapsulating Metals: Concept, Application, and Perspective [J].

Deng, Jiao ;

Deng, Dehui ;

Bao, Xinhe .

ADVANCED MATERIALS, 2017, 29 (43)

← 1 2 3 4 5 6 7 →