Influence of potassium addition on phosphorus availability and heavy metals immobility of biochar derived from swine manure

被引：4

作者：

Liu, Tingwu ^{[1
]}

Shao, Tianci ^{[1
]}

Jiang, Jinling ^{[1
]}

Ma, Wenge ^{[1
]}

Feng, Ranran ^{[1
]}

Dong, Dan ^{[1
]}

Wang, Yan ^{[1
]}

Bai, Tianxia ^{[1
]}

Xu, Yonggang ^{[1
]}

机构：

[1] Huaiyin Normal Univ, Collaborat Innovat Ctr Reg Modern Agr & Environm P, Jiangsu Key Lab Ecoagr Biotechnol Hongze Lake, Huaian 223300, Peoples R China

来源：

SCIENTIFIC REPORTS | 2024年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Swine manure; Biochar; Phosphorus; Heavy metals; Silicon; SPECIATION; PYROLYSIS; PLANT; BIOAVAILABILITY; RISK; ZN; CU;

D O I：

10.1038/s41598-024-69761-1

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Pyrolysis of animal manure at high temperature is necessary to effectively immobilize heavy metals, while the available phosphorus (P) level in biochar is relatively low, rendering it unsuitable for use as fertilizer. In this study, the pretreatment of swine manure with different potassium (K) sources (KOH, K2CO3, CH3COOK and C6H5K3O7) was conducted to produce a biochar with enhanced P availability and heavy metals immobility. The addition of all K compounds lowered the peak temperature of decomposition of cellulose in swine manure. The percentage of ammonium citrate and formic acid extractable P in biochar increased with K addition compared to undoped biochar, with CH3COOK and C6H5K3O7 showing greater effectiveness than KOH and K2CO3, however, water- extractable P did not exhibit significant changes. Additionally, the available and dissolved Si increased due to the doping of K, with KOH and K2CO3 having a stronger effect than CH3COOK and C6H5K3O7. X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) analysis revealed that K addition led to the formation of soluble CaKPO4 and silicate. In addition, the incorporation of K promoted the transformation of labile copper (Cu) and znic (Zn) into the stable fraction while simultaneously reducing their environmental risk. Our study suggest that the co-pyrolysis of swine manure and organic K represents an effective and valuable method for producing biochar with optimized P availability and heavy metals immobility.

引用

页数：10

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