Beyond CO 2 reduction: Electrochemical C-N coupling reaction for

被引：3
作者：
Kim, Dohun [1 ]
Eo, Jungsu [1 ]
Lim, Seolha [1 ]
Nam, Dae-Hyun [1 ]
机构：
[1] Daegu Gyeongbuk Inst Sci & Technol DGIST, Dept Energy Sci & Engn, Daegu 42988, South Korea
来源：
CURRENT OPINION IN ELECTROCHEMISTRY | 2024年 / 46卷
基金：
新加坡国家研究基金会;
关键词：
Organonitrogen electrosynthesis; Electrocatalysts; C-N coupling reactions; Co-reduction; CARBON-DIOXIDE; ELECTROCATALYTIC REDUCTION; CONVERSION; NITRATE; UREA; IONS;
D O I：
10.1016/j.coelec.2024.101491
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The electrosynthesis of organonitrogen compounds via coreduction of carbon dioxide (CO2) and nitrogenous molecules is regarded as a promising green technology for sustainable and reliable chemical production. Although many researchers have reported on electrochemical C-N coupling reactions, these reactions are still insufficient for use in the commercial industry. In this work, we provide a comprehensive review of the fundamental reaction mechanism of electrochemical C-N coupling and strategies for improving the electrosynthesis of organonitrogen compounds. Additionally, we discuss the current challenges, extended electrochemical coupling reactions, and future roadmaps of electrochemical C-N coupling reactions. This review will strongly enhance the understanding of electrochemical C-N coupling reactions and propose a way forward for the electrosynthesis of organonitrogen compounds.
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页数：9
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