Utilization of Silicon for Lithium-Ion Battery Anodes: Unveiling Progress, Hurdles, and Prospects (Review)

被引：0
作者：
Ashurov I. [1 ]
Akhunov K. [1 ]
Ashurov K. [1 ]
Wang H. [2 ]
Wang G. [3 ]
Ji P. [3 ]
Kurbanov M. [1 ]
机构：
[1] Arifov Institute of Ion-Plasma and Laser Technologies, Uzbekistan Academy of Sciences, Tashkent
[2] School of Chemistry, Beijing Advanced Innovation Center for Biomedical Engineering, Beihang University, Beijing
[3] School of Materials Science and Engineering, Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology, Hebei University of Technology, Tianjin
来源：
Applied Solar Energy (English translation of Geliotekhnika) | 2024年 / 60卷 / 01期
关键词：
electrochemical performance; energy storage systems; lithium-ion batteries; next generation batteries; Si-based anode materials;
D O I：
10.3103/S0003701X23601801
中图分类号：
学科分类号：
摘要：
Abstract: Within the lithium-ion battery sector, silicon (Si)-based anode materials have emerged as a critical driver of progress, notably in advancing energy storage capabilities. The heightened interest in Si-based anode materials can be attributed to their advantageous characteristics, which include a high theoretical specific capacity, a low delithiation potential, wide availability, and cost-effectiveness. However, these materials are not immune to challenges. One prominent issue arises from the significant volume changes that occur during lithiation (charging) and delithiation (discharging) processes, resulting in mechanical stress within the material. This stress leads to structural degradation over time, thereby reducing capacity and performance. Another critical concern revolves around the inherent low electronic conductivity of Si-based materials and their limited cycling stability, which limits their practical application on a commercial scale. This comprehensive review thoroughly examines recent advancements in SiOx (0 < x ≤ 2)-based anode materials, with a specific focus on SiO2 and Si-carbon composites, delving into their electrochemical properties and mechanisms. It also highlights existing challenges and suggests potential avenues for improvement, providing valuable insights for future research directions. The synthesis methods and performance benchmarks discussed in this review are essential for developing more efficient and sustainable SiOx-based anodes across various energy storage applications. © Allerton Press, Inc. 2024. ISSN 0003-701X, Applied Solar Energy, 2024, Vol. 60, No. 1, pp. 90–126. Allerton Press, Inc., 2024.
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页码：90 / 126
页数：36
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