Harnessing enhanced stability and high-rate capability in lithium-ion batteries using synergistic SnS 2 /MoS 2 2D nanostructures with optimized conversion/alloying reactions

被引:1
作者
Venugopal, Boya [1 ,2 ,3 ]
Mudike, Ravi [4 ]
Ravi, Ranjith [5 ]
Sahoo, Prasanta Kumar [6 ]
Tripathi, Abhishek [7 ]
Shown, Indrajit [1 ,5 ]
机构
[1] Acad Sinica, Inst Atom & Mol Sci, Taipei 10617, Taiwan
[2] Acad Sinica, Taiwan Int Grad Program, Nanosci & Technol Program, Taipei 11529, Taiwan
[3] Natl Tsing Hua Univ, Dept Engn & Syst Sci, Hsinchu 30013, Taiwan
[4] Minzu Univ China, Sch Sci, Beijing 100081, Peoples R China
[5] Hindustan Inst Technol & Sci, Dept Chem, Chennai 603103, India
[6] Natl Inst Hydrol Jalvigyan Bhawan, Roorkee 247667, India
[7] Malaviya Natl Inst Technol, Dept Met & Mat Engn, Jaipur 302017, India
关键词
Lithium -ion battery; SnS; 2; /MoS; anode; 2D nanostructure; Cyclic voltammetry; Anode material; HIGH-PERFORMANCE; GRAPHENE SHEETS; ANODE MATERIAL; NANOSHEETS; NANOPARTICLES; CAPACITY;
D O I
10.1016/j.jallcom.2024.173886
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, there has been a significant interest in the application of SnS 2 /MoS 2 2D nanostructure composites in lithium -ion batteries (LIBs) due to their advantageous conversion, intercalation, and alloying reactions, leading to high capacity during charge and discharge cycles. In this study, we successfully synthesized SnS 2 /MoS 2 composites with a 2D-nanoplate morphology using a single-step hydrothermal method. Specifically, the optimized SnS 2 /MoS 2 -3:1 composite was tested as anodes in coin cell LIBs, demonstrating an impressive capacity of 710 mAh/g at a current density of 500 mA/g, along with outstanding stability (800 cycles) and remarkable rate capability compared to other composites. The excellent electrochemical performance of the SnS 2 /MoS 2 -3:1 composite can be attributed to the moderately coupled SnS 2 and MoS 2 2D-nanosheets, which provide short lithium -ion transportation lengths, low charge transfer resistance, and dominant capacitive behavior.
引用
收藏
页数:9
相关论文
共 25 条
  • [1] Interlayer expansion of few-layered Mo-doped SnS2 nanosheets grown on carbon cloth with excellent lithium storage performance for lithium ion batteries
    Chen, Qiang
    Lu, Fengqi
    Xia, Ying
    Wang, Hai
    Kuang, Xiaojun
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (08) : 4075 - 4083
  • [2] A synergistic "cascade" effect in copper zinc tin sulfide nanowalls for highly stable and efficient lithium ion storage
    Chiu, Jian-Ming
    Chou, Tsu-Chin
    Wong, Deniz P.
    Lin, Yi-Rung
    Shen, Chin-An
    Hy, Sunny
    Hwang, Bing-Joe
    Tai, Yian
    Wu, Heng-Liang
    Chen, Li-Chyong
    Chen, Kuei-Hsien
    [J]. NANO ENERGY, 2018, 44 : 438 - 446
  • [3] Carbon-coated SnO2 riveted on a reduced graphene oxide composite (C@SnO2/RGO) as an anode material for lithium-ion batteries
    Dai, Yao
    Li, Fu
    Fu, Yuan-Xiang
    Mo, Dong-Chuan
    Lyu, Shu-Shen
    [J]. RSC ADVANCES, 2021, 11 (15) : 8521 - 8529
  • [4] Performance and resource considerations of Li-ion battery electrode materials
    Ghadbeigi, Leila
    Harada, Jaye K.
    Lettiere, Bethany R.
    Sparks, Taylor D.
    [J]. ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (06) : 1640 - 1650
  • [5] Three-Dimensional Network Architecture with Hybrid Nanocarbon Composites Supporting Few-Layer MoS2 for Lithium and Sodium Storage
    Hu, Xiang
    Li, Yan
    Zeng, Guang
    Jia, Jingchun
    Zhan, Hongbing
    Wen, Zhenhai
    [J]. ACS NANO, 2018, 12 (02) : 1592 - +
  • [6] Sandwich-like SnS2/Graphene/SnS2 with Expanded Interlayer Distance as High-Rate Lithium/Sodium-Ion Battery Anode Materials
    Jiang, Yong
    Song, Daiyun
    Wu, Juan
    Wang, Zhixuan
    Huang, Shoushuang
    Xu, Yi
    Chen, Zhiwen
    Zhao, Bing
    Zhang, Jiujun
    [J]. ACS NANO, 2019, 13 (08) : 9100 - 9111
  • [7] Rationally Incorporated MoS2/SnS2 Nanoparticles on Graphene Sheets for Lithium-Ion and Sodium-Ion Batteries
    Jiang, Yong
    Guo, Yibo
    Lu, Wenjun
    Feng, Zhenyu
    Xi, Baojuan
    Kai, Shuangshuang
    Zhang, Junhao
    Feng, Jinkui
    Xiong, Shenglin
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2017, 9 (33) : 27697 - 27706
  • [8] Morphology engineering of silicon nanoparticles for better performance in Li-ion battery anodes
    Lai, Samson Y.
    Maehlen, Jan Petter
    Preston, Thomas J.
    Skare, Marte O.
    Nagell, Marius U.
    Ulvestad, Asbjorn
    Lemordant, Daniel
    Koposov, Alexey Y.
    [J]. NANOSCALE ADVANCES, 2020, 2 (11): : 5335 - 5342
  • [9] Stable high-areal-capacity nanoarchitectured germanium anodes on three-dimensional current collectors for Li ion microbatteries
    Lee, Gwang-Hee
    Lee, Seun
    Lee, Chan Woo
    Choi, Changhoon
    Kim, Dong-Wan
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (03) : 1060 - 1067
  • [10] Surface-Initiated Growth of Thin Oxide Coatings for Li-Sulfur Battery Cathodes
    Lee, Kyu Tae
    Black, Robert
    Yim, Taeeun
    Ji, Xiulei
    Nazar, Linda F.
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (12) : 1490 - 1496