Preparation of reprocessable cross-linked polymers via dynamic covalent bonds

被引：0

作者：

Wu K.-H. ^{[1
]}

Gu X.-P. ^{[1
]}

Feng L.-F. ^{[1
]}

Zhang C.-L. ^{[1
]}

机构：

[1] State Key Laboratory of Chemical Engineering, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou

来源：

Gao Xiao Hua Xue Gong Cheng Xue Bao/Journal of Chemical Engineering of Chinese Universities | 2020年 / 34卷 / 01期

关键词：

Cross-linking; Dynamic covalent bond; Dynamic covalent chemistry; Reprocessing;

D O I：

10.3969/j.issn.1003-9015.2020.01.001

中图分类号：

学科分类号：

摘要：

Cross-linked polymer networks with highly cross-linking chemical structures constructed via dynamic covalent bonds can provide polymers with excellent physical and mechanical properties, and also good self-healing ability and reprocessability through chain rearrangement. The technique shows great potential application in industry by breaking the boundaries between thermoplastic and thermoset polymers. In this review, based on dynamic covalent mechanisms of transesterification, disulfide exchange, siloxane silanol exchange, olefin cross-metathesis, imine exchange and acylhydrazone exchange reactions, preparation and properties of reprocessable cross-linked polymers with these dynamic covalent bonds are introduced in detail. Furthermore, existing problems and development prospects in dynamic covalent cross-linked polymers are discussed. © 2020, Editorial Board of Journal of Chemical Engineering of Chinese Universities". All right reserved."

引用

页码：1 / 8

页数：7

共 48 条

[1]

Cao Q.X., Current development status and policies need to be perfected of China's waste rubber industry, China Rubber, 33, 11, pp. 21-25, (2017)

[2]

Rowan S.J., Cantrill S.J., Cousins G.R.L., Et al., Dynamic covalent chemistry, Angewandte Chemie International Edition, 41, 22, pp. 898-952, (2002)

[3]

Corbett P.T., Leclaire J., Vial L., Et al., Dynamic combinatorial chemistry, Chemical Reviews, 106, 9, pp. 3652-3711, (2006)

[4]

Zheng N., Xie T., Thermadapt shape memory polymer, Acta Polymerica Sinica, 11, pp. 1715-1724, (2017)

[5]

Zhang Z.P., Rong M.Z., Zhang M.Q., Research progress of processing of crosslinked polymers based on reversible covalent chemistry: a new challenge to the development of polymer engineering, Acta Polymerica Sinica, 7, pp. 829-852, (2018)

[6]

Capelot M., Unterlass M.M., Tournilhac F., Et al., Catalytic control of the vitrimer glass transition, ACS Macro Letters, 1, 7, pp. 789-792, (2012)

[7]

Montarnal D., Capelot M., Tournilhac F., Et al., Silica-like malleable materials from permanent organic networks, Science, 334, 6058, pp. 965-968, (2011)

[8]

Yu K., Taynton P., Zhang W., Et al., Influence of stoichiometry on the glass transition and bond exchange reactions in epoxy thermoset polymers, RSC Advances, 4, 89, pp. 48682-48690, (2014)

[9]

Yu K., Taynton P., Zhang W., Et al., Reprocessing and recycling of thermosetting polymers based on bond exchange reactions, RSC Advances, 4, 20, pp. 10108-10117, (2014)

[10]

Capelot M., Montarnal D., Tournilhac F., Et al., Metal-catalyzed transesterification for healing and assembling of thermosets, Journal of the American Chemical Society, 134, 18, pp. 7664-7667, (2012)

← 1 2 3 4 5 →