Novel nanocomposite made of calcium zinc silicate/ NiO2 for biomedical applications

被引:3
|
作者
Sherif, H. H. A. [1 ]
Hamzawy, E. M. A. [2 ]
El Zawawi, I. K. [3 ]
Kenawy, S. H. [4 ]
El-Bassyouni, Gehan T. [4 ]
Mahdy, Manal A. [3 ]
机构
[1] Natl Res Ctr, Spect Dept, 33 El Buhouth St, Giza 12622, Egypt
[2] Natl Res Ctr NRC, Glass Res Dept, 33 El Buhouth St, Giza 12622, Egypt
[3] Natl Res Ctr, Solid State Phys Dept, 33 El Buhouth St, Giza 12622, Egypt
[4] Natl Res Ctr, Refractories Ceram & Bldg Mat Dept, 33 El Buhouth St, Giza 12622, Egypt
关键词
Calcium zinc silicate/NiO(2 )composites; Wollastonite and willemite; Nano-scale structure; Structural properties; Surface morphology; Optical magnetic and antimicrobial properties; OXIDE; ANTIBACTERIAL; SCAFFOLDS; BIOCOMPATIBILITY; TEMPERATURE;
D O I
10.1016/j.ceramint.2024.01.155
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The novel nanocomposites of ZnO-containing CaSiO3/NiO2 were prepared through the wet precipitation method. The XRD of samples sintered at 1100 degrees C/2 h presented variable phases, mainly hardystonite (Ca2ZnSi2O7) with two secondary phases of willemite (Zn2SiO4) and tridymite (SiO2). Similarly, small diffraction peaks of peroxide nickel oxide (NiO2) arose in samples containing significant concentrations of it. All composites were crystallized in the nano-range, and their particle sizes (Ps) range from 60 to 70 nm. According to the morphological investigation, the percentage of NiO2 increased grain size. The optical result assured that the willemite phase has an optical band gap of 5.35-5.58 eV and a minor transition at similar to 3.4 eV. While NiO2 had a small transition found at 1.7 +/- 0.05 eV. The lattice vibrations of Ca-O, the stretching of the C-O group in CaCO3, and the Si-O symmetric stretching were affected by the NiO2 concentration, as evident from the Raman spectra. Nevertheless, the FTIR result revealed that the increasing NiO2 concentration did not affect the stretching and bending vibrations of the composites. The values of moment/g increased with NiO2, and two magnetic contributions were revealed. The concentration of NiO2 in the composite was shown to be connected to the composite's ability to suppress the various microbiological strains tested. There is no detectable inhibitory impact when the sample's NiO2 content is less than 3%. This research topic provides an opportunity to look into novel materials with possible antimicrobial uses for infection prevention in biological fields, such as bone repair.
引用
收藏
页码:12459 / 12471
页数:13
相关论文
共 50 条
  • [1] Study of Bioactive Calcium Silicate Ceramic Systems for Biomedical Applications
    Meiszterics, A.
    Sinko, K.
    5TH EUROPEAN CONFERENCE OF THE INTERNATIONAL FEDERATION FOR MEDICAL AND BIOLOGICAL ENGINEERING, PTS 1 AND 2, 2012, 37 : 1098 - 1101
  • [2] Recent advances on akermanite calcium-silicate ceramic for biomedical applications
    Zadehnajar, Parisa
    Mirmusavi, Mohammad Hussein
    Soleymani Eil Bakhtiari, Sanaz
    Bakhsheshi-Rad, Hamid Reza
    Karbasi, Saeed
    RamaKrishna, Seeram
    Berto, Filippo
    INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY, 2021, 18 (06) : 1901 - 1920
  • [3] Novel Antibacterial and Bioactive Silicate Glass Nanoparticles for Biomedical Applications
    Vale, Ana Catarina
    Carvalho, Ana Luisa
    Barbosa, Ana Margarida
    Torrado, Egidio
    Mano, Joao F.
    Alves, Natalia M.
    ADVANCED ENGINEERING MATERIALS, 2018, 20 (05)
  • [4] A Review on Calcium Silicate Ceramics: Properties, Limitations, and Solutions for Their Use in Biomedical Applications
    Youness, Rasha A.
    El-deen, Doha M. Tag
    Taha, Mohammed A.
    SILICON, 2023, 15 (06) : 2493 - 2505
  • [5] Mechanical and physical properties of calcium silicate/alumina composite for biomedical engineering applications
    Shirazi, F. S.
    Mehrali, M.
    Oshkour, A. A.
    Metselaar, H. S. C.
    Kadri, N. A.
    Abu Osman, N. A.
    JOURNAL OF THE MECHANICAL BEHAVIOR OF BIOMEDICAL MATERIALS, 2014, 30 : 168 - 175
  • [6] Electrodeposition of porous hydroxyapatite/calcium silicate composite coating on titanium for biomedical applications
    Huang, Yong
    Han, Shuguang
    Pang, Xiaofeng
    Ding, Qionqion
    Yan, Yajing
    APPLIED SURFACE SCIENCE, 2013, 271 : 299 - 302
  • [7] A Review on Calcium Silicate Ceramics: Properties, Limitations, and Solutions for Their Use in Biomedical Applications
    Rasha A. Youness
    Doha M. Tag El-deen
    Mohammed A. Taha
    Silicon, 2023, 15 : 2493 - 2505
  • [8] Synthesis and structural properties characterization of titania/zirconia/calcium silicate nanocomposites for biomedical applications
    AbuShanab, Waheed S.
    Moustafa, Essam B.
    Taha, Mohammed A.
    Youness, Rasha A.
    APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2020, 126 (10):
  • [9] Synthesis and structural properties characterization of titania/zirconia/calcium silicate nanocomposites for biomedical applications
    AbuShanab, Waheed S.
    Moustafa, Essam B.
    Taha, Mohammed A.
    Youness, Rasha A.
    Youness, Rasha A. (rhakamnrc@gmail.com), 1600, Springer (126):
  • [10] ANTIMICROBIAL EFFECTS OF FORMABLE GELATINOUS HYDROXYAPATITE-CALCIUM SILICATE NANOCOMPOSITES FOR BIOMEDICAL APPLICATIONS
    Chen, Hsin
    Lee, Dong-Joon
    Zhang, He
    Arnold, Roland
    Ko, Ching-Chang
    ADVANCES IN BIOCERAMICS AND POROUS CERAMICS VII, 2015, : 25 - 32