Synthesis of CuMnOx catalysts by using various precipitants for oxidation of carbon monoxide

被引:8
作者
Dey, S. [1 ]
Mehta, N. S. [2 ]
机构
[1] Rajiv Gandhi Proudyogiki Vishwavidyalaya, Environm Engn Dept, Bhopal, India
[2] Roorkee Coll Engn, Dept Elect & Commun, Roorkee, India
来源
RESOURCES ENVIRONMENT AND SUSTAINABILITY | 2021年 / 4卷
关键词
Carbon monoxide; Hopcalite catalyst; Co-precipitation method; Calcinations and characterization; MANGANESE OXIDE CATALYSTS; CO OXIDATION; HOPCALITE CATALYST; COPPER; ROUTE;
D O I
10.1016/j.resenv.2021.100025
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Hopcalite (CuMnOx) is one of the best catalysts for carbon monoxide (CO) oxidation at ambient conditions. In present research work we measured the performances of various precipitants (KMnO4, Na2CO3 and KOH) used in the CuMnOx catalysts synthesis by the co-precipitation method and calcined at 300 degrees C temperature. The KMnO4 precipitant used in CuMnOx catalyst has shown that the best catalytic activity, which completely oxidized CO at the lower temperature (T100 = 83 degrees C). The other precipitants used in CuMnOx catalyst synthesis by Na2CO3 as precipitant for CO oxidation was done at (T100=105 degrees C) and KOH used as precipitant in CuMnOx catalyst, which completely oxidized CO (T100=115 degrees C). The calcinations conditions of precursors have huge impact on the performances of resulting catalysts for CO oxidation. The reactive calcinations (RC) conditions (1.5% CO in air) prepared CuMnOx catalysts have shown that the best catalytic activity as compared to the tradition calcinations conditions. The RC route is one of the best calcinations strategies for preparation of highly active CuMnOx catalyst for CO oxidation.
引用
收藏
页数:11
相关论文
共 70 条
[1]  
Aguila J., 1991, Technical support document
[2]  
Alfuso S., 1993, SAE Paper 932801
[3]  
[Anonymous], 2016, India Bharat Stage VI Emission Standards. Policy Update
[4]  
[Anonymous], 1991, publication no. EPA-600/B-90/045F
[5]  
[Anonymous], 1994, EPA400-F-92-005
[6]   CARBON-MONOXIDE CONCENTRATION IN THE EARTHS ATMOSPHERE [J].
BADR, O ;
PROBERT, SD .
APPLIED ENERGY, 1994, 49 (02) :99-143
[7]  
Bhandarkar S., 2013, VEHICLE ENG, V1, P33
[8]   The choice of precipitant and precursor in the co-precipitation synthesis of copper manganese oxide for maximizing carbon monoxide oxidation [J].
Cai, Li-Na ;
Guo, Yue ;
Lu, An-Hui ;
Branton, Peter ;
Li, Wen-Cui .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2012, 360 :35-41
[9]  
Chhatwal G.R., 1975, Environmental Air Pollution and its Control
[10]  
Cholakov G.S., 2010, Pollut Control Technol, V3, P1