Multi-scale microstructure manipulation of an additively manufactured CoCrNi medium entropy alloy for superior mechanical properties and tunable mechanical anisotropy

Laser beam powder bed fusion (PBF-LB) additive manufacturing (AM) technology has become a versatile tool for producing new microstructures in metal components, offering novel mechanical properties for different applications. In this work, enhanced ductility (-55% elongation) and tunable mechanical anisotropy (ratio of ductility along vertical to horizontal orientation from -0.2 to -1) were achieved for a CoCrNi medium entropy alloy (MEA) by multi-scale synergistic microstructure manipulation (i.e., melt pool boundary, grain morphology and crystallographic texture) through adjusting key PBF-LB processing parameters (e.g., laser power and scan speed). By increasing the volumetric energy density (VED) from 68.3 to 144 J/mm(3), the melt pool size enlarges, and the crystallographic texture transitions from <100>//BD to <110>//BD due to the maximum thermal flux direction changing for different melt pool dimensions, which affects the proportion of grains that have different growth directions. Moreover, excellent mechanical properties of 890 MPa ultimate tensile strength and -55% elongation to failure can be achieved for loading perpendicular to the build direction with only a -15% reduction in properties for loading along the build direction. The superior combination of mechanical properties is achieved by processing parameter-controlled strengthening of melt pool boundary interfaces, heterogeneous deformation induced strengthening through bimodal grain structures, and favorable grain orientation for dislocation slip and twinning formation, which was significantly more activated in the <110>//BD texture than in the <100>//BD. This study offers new insights into achieving multi-scale synergistic microstructure manipulation via PBF-LB for desired strength, ductility, and mechanical anisotropy in a CoCrNi MEA.