Due to low early strength and high shrinkage, ordinary Portland cement (OPC) has difficulty meeting the actual needs of modern construction projects, while belite calcium sulfoaluminate cement (BCSA-OPC) composite cement provides a new solution. The mechanical and the drying shrinkage properties of the BCSA-OPC mortar were determined, the hydration heat of the BCSA-OPC was studied, and the pore size distribution of the mortar was investigated. In addition, the hydration products of the BCSA-OPC were analyzed by X-ray diffraction (XRD) and simultaneous thermal analysis (TG-DSC), and the microscopic morphology of the BCSA-OPC mortar was observed by scanning electron microscopy (SEM). The results show that with the increase in BCSA dosage in the BCSA-OPC, compared with OPC, the flexural strengths of the mortar of 50% dosage of BCSA at the hydration age of 1 d, 3 d, 7 d, and 28 d are improved by 33.3%, 36.6%, 23.6%, and 26.8%, and the compressive strengths are improved by 50.8%, 35.7%, 13.4%, and 27.7%. The drying shrinkage and total porosity of the mortar at the hydration age of 28 d are reduced by 117.4% and 21.55%, respectively. It is attributed to the filling effect of a large amount of ettringite (AFt) and intertwined with the fibrous C-S-H gel to form a network. This study will provide a theoretical basis for the application of the BCSA-OPC engineering.