Platinum and gold activated ZnFe2O4 nanomaterials for boosting photocatalytic inhibition of bacteria under visible light

被引:4
|
作者
Faizan, Muhammad [1 ]
Khan, Afaq Ullah [2 ]
Tahir, Kamran [1 ]
Almarhoon, Zainab M. [3 ]
Khan, Zia Ul Haq [9 ]
Alkudaisi, Nora Awad [4 ]
Alabbosh, Khulood Fahad [5 ]
Alanazi, Abdulaziz A. [6 ]
Al-Saeedi, Sameerah I. [7 ]
Zaki, Magdi E. A. [8 ]
机构
[1] Gomal Univ, Inst Chem Sci, Dera Ismail Khan, Khyber Pakhtunk, Pakistan
[2] Jiangsu Univ, Sch Chem & Chem Engn, 301 Xuefu Rd, Zhenjiang 212013, Peoples R China
[3] King Saud Univ, Coll Sci, Chem Dept, POB 2455, Riyadh 11451, Saudi Arabia
[4] Imam Abdulrahman bin Faisal Univ, Coll Sci, Dept Phys, POB 1982, Dammam 31441, Saudi Arabia
[5] Univ Hail, Coll Sci, Dept Biol, Hail, Saudi Arabia
[6] Prince Sattam bin Abdulaziz Univ, Coll Sci & Humanities Al Kharj, Dept Chem, Al Kharj 11942, Saudi Arabia
[7] Princess Nourah bint Abdulrahman Univ, Coll Sci, Dept Chem, POB 84428, Riyadh 11671, Saudi Arabia
[8] Imam Mohammad Ibn Saud Islamic Univ, Coll Sci, Dept Chem, Riyadh 11623, Saudi Arabia
[9] COMSATS Univ Islamabad, Dept Chem, Pk Rd, Islamabad 45550, Pakistan
来源
关键词
PtAu/ZnFe2O4; Hydrothermal process; Photocatalysis; Antibacterial activity; HYDROGEN GENERATION; BIMETALLIC NANOPARTICLES; METAL NANOPARTICLES; TIO2; NANOSHEETS; PARTICLE-SIZE; AU-PT; WATER; DEGRADATION; ZNO; ENHANCEMENT;
D O I
10.1016/j.mtcomm.2024.108383
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We successfully synthesized visible-light-activated magnetic photocatalysts, namely PtAu/ZnFe2O4, by modified hydrothermal process in which ascorbic acid was used as a reducing and stabilizing agent for the reduction of Pt and Au nanoparticles. These photocatalysts have the ability to use visible light for photocatalytic reactions and also exhibits magnetic properties. Photocatalytic tests conducted in this study showed that PtAu/ZnFe2O4 composites have greater photocatalytic performance under visible light. These composites, obviously improved have shown effectiveness against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Moreover, the analysis of charge carrier density presented that the addition of Pt and Au to ZnFe2O4 resulted in an increased fragmentation of the photogenerated charge carriers. This finding suggests that the said metals introduced enhance the overall photocatalysis performance by significantly facilitating charge carrier separation Application. Trapping experiments indicating reactive species such as O-center dot(2)- (superoxide) ions and h(+) (pores) in PtAu/ ZnFe2O4 performs a key role in the photocatalytic process. Furthermore, the as-prepared PtAu/ZnFe2O4 composite can be efficiently separated through external magnetic field after the photocatalytic reaction. Additionally, the hybrid materials displayed extremely effectual photocatalytic antibacterial property. The antibacterial activity was much proficient in light (E. coli inhibition zone= 17, and S. aureus inhibition zone = 19) than in dark (E. coli inhibition zone= 09, and S. aureus inhibition zone = 11). Taken together, these findings highlight the promising potential of the PtAu/ZnFe2O4 photocatalyst as a magnetic photocatalyst with antibacterial properties for practical applications in wastewater treatment. This research opens up avenues for the future development and implementation of photocatalysis in addressing environmental challenges associated with wastewater treatment.
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页数:13
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