Progresses of hyperpolarized 129 Xe NMR application in porous materials and catalysis

被引:8
|
作者
Fan, Benhan [1 ,3 ]
Xu, Shutao [1 ]
Wei, Yingxu [1 ]
Liu, Zhongmin [1 ,2 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy iChEM Collaborat Inno, Natl Engn Lab Methanol Olefins, Dalian 116023, Peoples R China
[2] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[3] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
关键词
Solid-state NMR; Hyperpolarized129Xe; Review; Porous materials; Catalysis; SOLID-STATE NMR; POLARIZED NOBLE-GASES; IN-SITU NMR; NUCLEAR-MAGNETIC-RESONANCE; XE-129; NMR; HETEROGENEOUS CATALYSIS; CHEMICAL-SHIFT; REAGENT FLOW; XENON; SURFACE;
D O I
10.1016/j.mrl.2021.100005
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
129 Xe NMR has been proven to be a powerful tool to investigate the structure of porous materials. Xenon is a monatomic noble gas which could be used as a probe due to the extremely sensitive to its local environment. Optical pumping techniques for production of hyperpolarized (HP) xenon have led to an increase of sensitivity up to orders of magnitude compared with traditional 129 Xe NMR. This review summarizes the application of this technique in porous materials and heterogeneous catalysis in recent ten years, involving of zeolites, metal-organic frameworks (MOFs), catalytic process and kinetics. (c) 2021 The Authors. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license (http:// creativecommons.org/licenses/by-nc-nd/4.0/).
引用
收藏
页码:11 / 27
页数:17
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