Epitaxial growth of AgCrSe2 thin films by molecular beam epitaxy

被引:1
作者
Nanao, Y. [1 ]
Bigi, C. [1 ]
Rajan, A. [1 ]
Vinai, G. [2 ]
Dagur, D. [2 ,3 ]
King, P. D. C. [1 ]
机构
[1] Univ St Andrews, Sch Phys & Astron, SUPA, St Andrews KY16 9SS, Scotland
[2] Ist Officina Materiali IOM CNR, Lab TASC, Area Sci Pk,SS14,Km 163-5, I-34149 Trieste, Italy
[3] Univ Trieste, Dept Phys, Via Alfonso Valerio 2, I-34127 Trieste, Italy
基金
英国工程与自然科学研究理事会; 欧洲研究理事会;
关键词
CRYSTAL; CONDUCTION;
D O I
10.1063/5.0184273
中图分类号
O59 [应用物理学];
学科分类号
摘要
AgCrSe2 exhibits remarkably high ionic conduction, an inversion symmetry-breaking structural transition, and is host to complex non-colinear magnetic orders. Despite its attractive physical and chemical properties and its potential for technological applications, studies of this compound to date are focused almost exclusively on bulk samples. Here, we report the growth of AgCrSe2 thin films via molecular beam epitaxy. Single-orientated epitaxial growth was confirmed by x-ray diffraction, while resonant photoemission spectroscopy measurements indicate a consistent electronic structure as compared to bulk single crystals. We further demonstrate significant flexibility of the grain morphology and cation stoichiometry of this compound via control of the growth parameters, paving the way for the targeted engineering of the electronic and chemical properties of AgCrSe2 in thin-film form.
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页数:6
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