Hydrothermal Processing,Characterization and Theoretical Calculations of a Copper(Ⅱ) Compound with 1,10-Phenanthroline Derivative Ligand:2-(4-Methoxyphenyl)-1H-imidazo[4,5-f][1,10] Phenanthroline

被引：1

作者：

黄艳菊 ^{[1
,2
]}

倪良 ^{[1
]}

朱彦煜 ^{[2
]}

姚加 ^{[3
]}

机构：

[1] School of Chemistry and Chemical Engineering,Jiangsu University

[2] Department of Chemistry,Tonghua Teachers College

[3] Department of Chemistry,Zhejiang University

来源：

结构化学 | 2012年 / 31卷 / 03期

关键词：

crystal structure; hydrothermal crystal growth; compounds; natural bond orbital;

D O I：

暂无

中图分类号：

O627.12 [铜族金属有机化合物];

学科分类号：

070303 ; 081704 ;

摘要：

The metal-organic compound [Cu(MOPIP)2(OH)2] 1(MOPIP = 2-(4-methoxy-phenyl)-1H-imidazo[4,5-f][1,10] phenanthroline) was hydrothermally synthesized and structurally characterized by elemental analysis,Fourier-transformed infrared spectroscopy,thermogravimetric analysis,single-crystal X-ray diffraction and theoretical calculations in Gaussian 03.In the crystal structure,the copper(Cu) atoms are tetra-coordinated with four different nitrogen atoms from two different MOPIP ligands,and the Cu atom is one of the five vertexes of the tetrahedron.Presumably due to the steric bulk of the phenyl ligands,compound 1 adopts a slightly distorted tetrahedral configuration.Moreover,it exhibits a zero-dimensional structure with Cu-MOPIP as the building units.Natural Bond Orbital(NBO) analysis was performed by using the NBO method built in Gaussian 03 Program.The calculation results showed a covalent interaction between the coordinated atoms and Cu(Ⅱ) ion.

引用

页码：353 / 360

页数：8

共 11 条

[1] Hydrothermal Syntheses and Crystal Structures of Two Metal-organic Complexes with 2,3-Pyridinedicarboxylic Acid and 2-Methyl-dipyrido[3,2-f:2',3'-h]quinoxaline Ligands [J].

黄艳菊 ;

倪良 ;

杜刚 ;

王蕾 .

结构化学, 2010, 29 (12) :1857-1863

[2] 由MOPIP配体构筑的两种金属配合物的合成、表征及晶体结构(英文) [J].

黄艳菊 ;

倪良 ;

杜刚 ;

崔运成 ;

张文莉 ;

王蕾 ;

郝向荣 .

无机化学学报, 2010, 26 (07) :1269-1273

[3] 由间苯二甲酸和Medpq配体构筑的一种新型零维铜(Ⅰ)的配合物的水热合成及晶体结构测定(英文) [J].

黄艳菊 ;

崔运成 ;

杜刚 .

无机化学学报, 2009, 25 (10) :1882-1884

[4]

Four metal–organic networks based on benzene-1,4-dioxyacetic acid and dipyrido[3,2-a:2′,3′-c]phenazine ligand[J] . Xiuying Li,Chunbo Liu,Guangbo Che,Xiangcheng Wang,Chunxiang Li,Yongsheng Yan,Qingfeng Guan.Inorganica Chimica Acta . 2010 (7)

[5]

Structural, spectroscopic and redox properties of transition metal complexes of dipyrido[3,2- f :2′,3′- h]-quinoxaline (dpq)[J] . Polyhedron . 2007 (14)

[6]

Ion pairing, H-bonding, and π–π interactions in copper(II) complex-organo-networks derived from a proton-transfer compound of the 1,10-phenanthroline-2,9-dicarboxylic acid[J] . Abolghasem Moghimi,Robabeh Alizadeh,Hossein Aghabozorg,Abbas Shockravi,M. Carla Aragoni,Francesco Demartin,Francesco Isaia,Vito Lippolis,Andrew Harrison,A. Shokrollahi,Mojtaba Shamsipur.Journal of Molecular Structure . 2005 (1)

[7]

Metal complexes of some thiocarbohydrazone ligands: synthesis and structure[J] . Azza A. A. Abu-Hussen,Adel A. A. Emara.Journal of Coordination Chemistry . 2004 (11)

[8]

Dithiosquarate (dtsq) complexes of nickel(II). Syntheses and crystal structures of[Ni(phen) 2 (1,2-dtsq)]·3.5H 2 O[Ni(phen) 2 (1,3-dtsq)] and[Ni(tren)(1,2-dtsq)][phen=1,10-phenanthroline;tren=tris(2-aminoethyl)amine][J] . M a Luisa Calatayud,Jorunn Sletten,Isabel Castro,Miguel Julve,Gunther Seitz,Klaus Mann.Inorganica Chimica Acta . 2003

[9]

Oxime and oximate metal complexes: unconventional synthesis and reactivity[J] . Vadim Yu. Kukushkin,Armando J.L. Pombeiro.Coordination Chemistry Reviews . 1999 (1)

[10]

Binuclear and polymeric copper(II) dicarboxylate complexes: syntheses and crystal structures of[Cu 2 (pda)(Phen) 4](ClO 4 ) 2 ?5H 2 O?C 2 H 5 OH[Cu 2 (oda)(Phen) 4](ClO 4 ) 2 ?2.67H 2 O?C 2 H 5 OH and {[Cu 2 (pda) 2 (NH 3 ) 4 (H 2 O) 2]?4H 2 O} n (odaH 2 =octanedioic acid;pdaH 2 =pentanedioic acid;Phen=1,10-phenanthroline)[J] . Michael Devereux,Malachy McCann,James F. Cronin,George Ferguson,Vickie McKee.Polyhedron . 1999 (16)

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