Two Ni~Ⅱ/Cu~Ⅱ Coordination Polymers Based on Pyridyl-carboxylate Ligand: Synthesis, Crystal Structures and Magnetic Properties

被引：1

作者：

叶骁 ^{[1
]}

董文文 ^{[1
]}

方义铭 ^{[1
]}

赵君 ^{[1
,2
]}

李东升 ^{[1
]}

机构：

[1] College of Material and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University

[2] Hubei Key Laboratory of Processing and Application of Catalytic Materials, Huanggang Normal University

来源：

结构化学 | 2018年 / 37卷 / 02期

基金：

中国国家自然科学基金;

关键词：

coordination polymers; crystal structure; NiⅡ/CuⅡ; compounds; magnetic property;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

Under hydrothermal conditions, the reactions of Ni~Ⅱ/Cu~Ⅱ ions with 3-(6-aminpyridinium-3-yl) benzoate(HL) afford two compounds [NiL 2]n(1) and [Cu L2(H2 O)]n(2). On the basis of X-ray diffraction analysis of the two compounds, the results show that compound 1 features one-dimensional(1 D) double-strand coordination arrays, while 2 presents the 63-hcb layers. Both compounds are further constructed into a 3 D supramolecular structure with the aid of weak secondary interactions. Thermal stabilities and magnetic properties of compounds 1 and 2 were also investigated.

引用

页码：322 / 328

页数：7

共 8 条

[1] A New Nickel(Ⅱ) Coordination Compound Constructed by Pyridyl-triazole and Oxybis(Benzoic Acid): Synthesis,Crystal Structure and the Effect on the Thermal Decomposition of Ammonium Perchlorate
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