A New 3D Metal-organic Framework with Tetranuclear Cadmium(II) Clusters: Synthesis, Structure, and Luminescent Property

被引：2

作者：

朱晓飞 ^{[1
]}

王宁 ^{[2
]}

谢晓燕 ^{[1
]}

侯瑞斌 ^{[1
]}

周德凤 ^{[1
]}

李亚丰 ^{[3
]}

胡君 ^{[1
]}

李新源 ^{[1
]}

刘鹤 ^{[1
]}

聂旺 ^{[1
]}

机构：

[1] School of Chemistry and Life Science, Changchun University of Technology

[2] School of Materials Science and Engineering, Nanyang Technological University

[3] School of Chemical Engineering, Changchun University of

来源：

结构化学 | 2014年 / 33卷 / 02期

关键词：

D O I：

暂无

中图分类号：

O627 [元素有机化合物];

学科分类号：

摘要：

A unique metal-organic framework [Cd2(L)1.5(μ3-OH)(H2 O)2 ]·2H2 O(1, H2 L = 2,5-dibenzoylterephthalic acid) has been synthesized under hydrothermal conditions, and characterized by single-crystal X-ray diffractions, elemental analyses, IR spectra and fluorescence spectrum. The compound is of triclinic system, space group P1, C33 H27 CdO14, Mr = 870.33, a = 12.2939(17), b = 12.5135(9), c = 13.2046(10), α = 115.3190(10), β = 96.9140(10), γ = 109.7950(10)°, V = 1641.6(3)3, Z = 2, Dc = 1.761 g/cm3, F(000) = 862, μ(MoK) = 1.366 mm-1, Rint = 0.0148, R = 0.0240 and wR = 0.0639 for 5995 observed reflections with I > 2σ(I). X-ray analysis shows that the title complex exhibits a 3D framework with(412·63) topology, in which the tetra-nuclear [Cd4(μ3-OH)2 ] clusters act as 6-connected nodes, and the L ligands can be simplified to be linear connectors. Moreover, the thermal stability and fluorescence have been studied in detail.

引用

页码：277 / 283

页数：7

共 50 条

[21] A new 3D lanthanide metal-organic framework based on fluorescent whitener: Synthesis, structures, and luminescent properties
D. B. Shi
Y. S. Xu
Russian Journal of Coordination Chemistry, 2014, 40 : 854 - 859
[22] A new 3D lanthanide metal-organic framework based on fluorescent whitener: Synthesis, structures, and luminescent properties
Shi, D. B.
Xu, Y. S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (11) : 854 - 859
[23] Synthesis, crystal structure and photo luminescent property of a 3D metal-organic hybrid of Cd(II) constructed by two different bridging carboxylate
BISWAJIT BHATTACHARYA
RAJDIP DEY
DEBAJYOTI GHOSHAL
Journal of Chemical Sciences, 2013, 125 : 661 - 666
[24] Synthesis, crystal structure and photo luminescent property of a 3D metal-organic hybrid of Cd(II) constructed by two different bridging carboxylate
Bhattacharya, Biswajit
Dey, Rajdip
Ghoshal, Debajyoti
JOURNAL OF CHEMICAL SCIENCES, 2013, 125 (03) : 661 - 666
[25] Hydrothermal synthesis, structure, fluorescence property of a novel 3D metal-organic framework with high thermal stability
Lei Wu
Ming Xue
Lin Huang
ShiLun Qiu
Science China Chemistry, 2011, 54 : 1441 - 1445
[26] A novel 3D microporous metal-organic framework of cadmium(II) oxalate with diamondoid network
Zhong, Rui-Qin
Zou, Ru-Qiang
Pandey, Daya S.
Kiyobayashi, Tetsu
Xu, Qiang
INORGANIC CHEMISTRY COMMUNICATIONS, 2008, 11 (09) : 951 - 953
[27] Hydrothermal synthesis, structure, fluorescence property of a novel 3D metal-organic framework with high thermal stability
Wu Lei
Xue Ming
Huang Lin
Qiu ShiLun
SCIENCE CHINA-CHEMISTRY, 2011, 54 (09) : 1441 - 1445
[28] Hydrothermal synthesis,structure,fluorescence property of a novel 3D metal-organic framework with high thermal stability
WU LeiXUE MingHUANG Lin QIU ShiLun State Key Laboratory of Inorganic Synthesis Preparative Chemistry
Jilin UniversityChangchun China
Science China(Chemistry), 2011, 54 (09) : 1441 - 1445
[29] The ionothermal synthesis of a 3D indium metal-organic framework: Crystal structure, photoluminescence property and photocatalytic activity
Ji, Wen-Juan
Zhai, Quan-Guo
Li, Shu-Ni
Jiang, Yu-Cheng
Hu, Man-Cheng
INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 24 : 209 - 211
[30] Hydrothermal synthesis,structure,fluorescence property of a novel 3D metal-organic framework with high thermal stability
WU Lei
Jilin University
Science China(Chemistry), 2011, (09) : 1441 - 1445

← 1 2 3 4 5 →