Syntheses,Crystal Structures and Properties of Two New Compounds from a Flexible Bipodal Acid with Additional Amide Groups

被引：1
|
作者：
徐涵 [1 ,2 ]
郑和根 [2 ]
机构：
[1] School of Chemistry and Chemical Engineering, Huangshan University
[2] School of Chemistry and Chemical Engineering, Nanjing University
来源：
结构化学 | 2017年 / 36卷 / 06期
基金：
中国国家自然科学基金;
关键词：
magnetic properties; reversible crystal-to-amorphous; bipodal flexible ligand;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
Two novel compounds {[Cu（IBG）(4,4-bipy)（H;O）;];·11H;O};（1） and {[Co（IBG）-（μ-H;O）(H;O);]·2H;O}n（2） based on isophthaloylbisglycine（H;IBG） have been synthesized and structurally characterized by thermogravimetric analysis, elemental analysis and single-crystal X-ray diffraction. Compound 1 shows a 1D chain sine/cosine chain structure, and compound 2 can be characterized as a 4-connected sql tetragonal planar network with the point symbol of {44·62}. Compound 2 has been characterized by magnetic measurements. In addition, 1 and 2 display an interesting reversible crystal-to-amorphous transformation.
引用
收藏
页码：1034 / 1042
页数：9
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