Synthesis,Crystal Structure and Luminescent Property of a New Indium(Ⅲ) Coordination Polymer

被引：1

作者：

杨贺

姜阳

徐波

李村成

机构：

[1] KeyLaboratoryofChemicalSensing&AnalysisinUniversitiesofShandong(UniversityofJinan),SchoolofChemistryandChemicalEngineering,UniversityofJinan

来源：

结构化学 | 2016年 / 35卷 / 11期

关键词：

coordination complex; crystal structure; luminescence; indium;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new coordination complex [In（pda）1.5（bpy）]_n（1, H2pda = 1,4-phenylenediacetic acid, bpy = 2,2?-bipyridine） has been synthesized under hydrothermal conditions and characterized by IR spectrum, elemental analysis, PXRD and single-crystal X-ray diffraction analysis. Crystal data for the title complex are as follows: monoclinic system, space group P21/n with a = 11.8015（7）, b = 15.9551（10）, c = 11.8858（8） ?, β = 94.844（6）o, V = 2230.0（2） ?3, Mr = 559.25, Z = 4, F（000） = 1124, Dc = 1.666 g/cm3, μ（Mo Kα） = 1.106 mm-1, R = 0.0269 and wR = 0.0569 for 4534 observed reflections with I > 2σ（I）. Complex 1 displays a 3D supermolecular structure based on the 1D zizag chains. Fluorescence spectrum measurement indicates that complex 1 shows strong fluorescence emission with a maximum peak at 447 nm in the solid state at room temperature.

引用

页码：1723 / 1727

页数：5

共 6 条

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