A Novel Copper(Ⅱ) Complex Based on 4-Amino-1,2,4-triazole Schiff-base:Synthesis,Crystal Structure,Spectral Characterization,and Hirshfeld Surface Analysis

被引：1
|
作者：
张海洋 [1 ]
肖瑜 [1 ]
朱芸 [1 ]
机构：
[1] Guangxi Collaborative Innovation Center for Water Pollution Control and Water Safety in Karst Area, Guangxi Colleges and Universities Key Laboratory of Heavy Metal Pollution Prevention Theory and Technology, Guilin University of Technology
来源：
结构化学 | 2017年 / 36卷 / 05期
基金：
中国国家自然科学基金;
关键词：
Schiff-base ligand; crystal structure; fluorescence; electrochemiluminescence; Hirshfeld surfaces analysis;
D O I：
暂无
中图分类号：
O641.4 [络合物化学（配位化学）];
学科分类号：
070304 ; 081704 ;
摘要：
A novel copper complex Cu2(L)4(1, HL = 2-ethoxy-6-([1,2,4]triazol-4-yliminomethyl)-phenol) has been synthesized and characterized by IR, single-crystal X-ray diffraction, and elemental analysis(CHN). The single crystal belongs to the triclinic system, space group P1 with a = 10.0991(10), b = 10.5280(12), c = 10.5777(11) ?, α = 97.230(9), β = 90.640(8), γ = 92.412(9)o, Mr = 1052.05, V = 1114.6(2) ?3, Z = 1, Dc = 1.567 g/cm3, F(000) = 542, μ = 1.029 mm–1, R = 0.0562 and w R = 0.1562. The fluorescence and electrochemiluminescence(ECL) of 1and HL ligand were studied. The luminescence properties of 1 can be attributed to the ligand-metal charge transfer.
引用
收藏
页码：848 / 855
页数：8
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