Synthesis, Crystal Structure and Property of Cu Pb2(OH)2Cl3

被引：1
|
作者：
黄荣荣 [1 ,2 ]
张素允 [2 ]
崔美艳 [2 ]
徐军 [1 ]
何长振 [2 ]
机构：
[1] College of Materials Science and Engineering, Wuhan Institute of Technology
[2] State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
来源：
结构化学 | 2015年 / 34卷 / 04期
关键词：
oxyhalide; crystal structure; hydrothermal reaction; semiconductor;
D O I：
暂无
中图分类号：
O627.12 [铜族金属有机化合物];
学科分类号：
摘要：
A new copper(I)-lead(II) oxyhalide, Cu Pb2(OH)2Cl3, has been prepared by hydrothermal reaction and structurally characterized by single-crystal X-ray analysis. The compound crystallizes in tetragonal, space group I4(1)/acd with a = b = 13.77(1), c = 15.38(1) , V = 2916.2(2), Z = 4, Mr = 618.29, Dc = 5.633 g/cm3, μ = 49.97(2) mm-1, F(000) = 4192, the final R = 0.0204 and w R = 0.0452 for 757 observed reflections with I > 2σ(I). The structure of Cu Pb2(OH)2Cl3 contains one-dimensional helical chains built by Cu Cl4 tetrahedra with corner-sharing along the c-axis, in which the Pb2+ and OH- ions are located at the voids between chains. Optical reflectance spectrum measurements indicate that it is a semiconductor with a band-gap of 3.23 e V.
引用
收藏
页码：594 / 598
页数：5
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