Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate

被引：0

作者：

王乐 ^{[1
]}

边玮玮 ^{[2
]}

朱凌 ^{[1
]}

倪荣军 ^{[1
]}

陶琳 ^{[1
]}

机构：

[1] State Key Laboratory of Ceramic,Zibo Entry and Exit Inspection and Quarantine Bureau

[2] Department of Medical Chemistry,Weifang Medical University

来源：

结构化学 | 2011年 / 30卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlo-rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide(L) with indium(iii) perchlorate,and its structure was characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal of the title compound([In(C8H9N4S)2]ClO4·H2O) belongs to monoclinic,space group P21/c with a = 12.6438(18),b = 12.6259(18),c = 15.116(2) nm,β = 105.800(2)°,Z = 4,V = 2321.9(6) nm3,Mr = 618.79,Dc = 1.770 g/cm3,μ = 1.359 mm-1,F(000) = 1240,R = 0.0265 and wR = 0.0675.X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.

引用

页码：882 / 886

页数：5

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