A Zn(Ⅱ) Coordination Polymer with 4-Connected bbf Topology: Synthesis, Crystal Structure and Luminescent Property

被引：1

作者：

张鑫 ^{[1
,2
]}

覃业燕 ^{[1
]}

孙明玲 ^{[1
]}

姚元根 ^{[1
]}

机构：

[1] Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

[2] University of Chinese Academy of Sciences

来源：

结构化学 | 2016年 / 35卷 / 07期

关键词：

Zn(Ⅱ) compound; topology; 3D framework; luminescence;

D O I：

暂无

中图分类号：

O641.4 [络合物化学（配位化学）];

学科分类号：

070304 ; 081704 ;

摘要：

A new Zn（Ⅱ） compound, namely {Zn（BTA）(pdc);};（1, HBTA = 1,2,3-benzotriazole, H;pdc = terephthalic acid）, has been hydrothermally synthesized and characterized by elemental analysis, infrared analysis, powder X-ray diffraction analysis and single-crystal X-ray structural analysis. The crystal structure is of monoclinic system, space group P21/c with a = 10.751（3）, b = 9.792（3）, c = 9.292（3） ?, β = 95.391（4）°, V = 973.9（5） ?3, C10H6N3O2 Zn, Mr = 265.57, Z = 4, Dc = 1.811 g/cm3, F（000） = 532, μ = 2.506 mm-1, R = 0.0221 and w R = 0.0605 for 2075 observed reflections(I > 2s（I）). Single-crystal X-ray structural analysis reveals that compound 1 features a three-dimensional（3D） framework with 4-connected bbf topology. Moreover, the thermogravimetric（TG） analysis and photoluminescent property of 1 were also discussed.

引用

页码：1145 / 1150

页数：6

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